アドレナリン生合成

%!compile=2
\documentclass[b5j,9pt]{tetsujsarticle}
\usepackage{tetsuchem}
\pagestyle{empty}% empty にするとヘッダ・フッタ類が全部消える

\余白設定[% デフォルトでは一行字数を四捨五入により整数zwに調整する。\余白設定* だと一行字数を切り上げで整数zwに調整，\余白設定** だと調整しない。
上余白=1truecm,
下余白=上余白,
左余白=1truecm,
左右差=0truecm,
段間隔=4zw,% B4横を2段組にしてB5縦を2枚並べたように見せるときには 段間隔=対称 とする。
段組の仕切り線の太さ=.5truept,
ヘッダの縦幅=16truept,
ヘッダ下端と本文上端の縦間隔=10truept,
ヘッダと本文を仕切る線の太さ=0truept,
本文下端とフッタ下端の縦間隔=20truept,
本文とフッタを仕切る線の太さ=0truept,
傍注領域の幅=0zw,
本文端と傍注領域との間隔=0truept,
傍注同士の縦間隔=\baselineskip,
奇数ページの傍注位置=右,
偶数ページの傍注位置=左,
]
%\段間隔調整{n}% n段組にしたときに一行字数が整数になるよう適切な段間隔に調整する。デフォルトでは現在の一行字数に最も近い字数に調整するが，\段間隔調整* だと一行字数を切り上げで整数zwに調整する。\段間隔調整** だと調整しない。

\begin{document}

%\setatomsep{2.6em}%%線の長さ指定。chemfigじゃなきゃ効かない
%\setbondoffset{2pt}


{\nousece\chemfig{[:-120]*6(-*5(-C(=O)-O-C(=O)-)=-=*5(-C(=O)-O-C(=O)-)-=)}}

\benzene

\benzenecirc

\Benzene

\Benzenecirc


\nijur{CH3}{O}{COOH}

\ce{O}\quinone\ce{O}

\ベンゼン置換体{1235}{CH3}{COOH}{OH}{H2N}

\不定二置換体{CH3}{COOH}

\br1

\setcrambond{3pt}{}{}

\br1

\chemnameinit{}\chemname{$n$\niju{R_1}{R_2}{R_3}{R_4}}{単量体}\quad\ce{->C[付加重合][]}\quad\chemname{\chemfig{-[@{open,.5},1.3] C(-[2]R_1)(-[-2]R_2) -[,1.5] C(-[2]R_3)(-[6]R_4) -[@{close,.5},1.3]}%
\polymerbracket{20pt}{20pt}{n}}{重合体}

\br1
\小見出し{アドレナリン生合成}

\br{.5}
\ihspace{2zw}\scalebox{0.9}{\chemnameinit{}\chemname{\parboxx{\benzenefig{[:60,1.3]*6(-=(-[,1.6]CH_2-[0,1.8]C(-[:60,1.8]C(=[:120,1.4]O) -[:0,1.6] OH)(<[:-60,1.8]NH_2)<:[0,1.8]H)-=-(-[,1.6]HO)=)}}}{\Lhyphen チロシン}}\ce{->C[][]}\scalebox{0.9}{\chemnameinit{}\chemname{\parboxx{\benzenefig{[:60,1.3]*6(-=(-[,1.6]CH_2-[0,1.8]C(-[:60,1.8]C(=[:120,1.4]O) -[:0,1.6] OH)(<[:-60,1.8]NH_2)<:[0,1.8]H)-=(-[,1.6]HO)-(-[,1.6]HO)=)}}}{\Lhyphen ドーパ}}\ce{->C[][]}\scalebox{0.9}{\chemnameinit{}\chemname{\parboxx{\benzenefig{[:60,1.3]*6(-=(-[,1.6]CH_2-[:-30,1.8]CH_2(-[:0,1.8]NH_2))-=(-[,1.6]HO)-(-[,1.6]HO)=)}}}{ドーパミン}}
\br{.5}


\noindent\ce{->C[][]}\scalebox{0.9}{\chemnameinit{}\chemname{\parboxx{\benzenefig{[:60,1.3]*6(-=(-[,1.4]C(<[:125,1.8]HO)(<:[:55,1.8]H)-[:-30,1.8]CH_2-[0,1.8]NH_2)-=(-[,1.6]HO)-(-[,1.6]HO)=)}}}{ノルアドレナリン}}\noindent\ce{->C[][]}\scalebox{0.9}{\chemnameinit{}\chemname{\parboxx{\benzenefig{[:60,1.3]*6(-=(-[,1.4]C(<[:125,1.8]HO)(<:[:55,1.8]H)-[:-30,1.8]CH_2-[0,1.8]N(-[:60,1.6]H)-[:-60,1.6]CH_3)-=(-[,1.6]HO)-(-[,1.6]HO)=)}}}{アドレナリン}}


\br1


\小見出し{生化学系}


\parbox{38zw}{\centering\chemnameinit{\nousece\chemfig{[:0]*6(?(=O)-N(-H)-=-(-NH_2)=N?)}}
\chemname{\nousece\chemfig{[:-36]*5(-\chembelow{N}{H}-(*6(-N=-N=?[b](-NH_2)))=?[b]-N=)}}{\hososikaku{ア}}
\ihspace{2.5zw}\chemname{\nousece\chemfig{[:-36]*5(-\chembelow{N}{H}-(*6(-N=(-NH_2)-[,,,1]NH-?[b](=O)))=?[b]-N=)}}{グアニン}
\ihspace{2.5zw}\chemname{\nousece\chemfig{[:0]*6(?(=O)-\chembelow{N}{H}-=-(-NH_2)=N?)}}{\hososikaku{イ}}
\ihspace{2.5zw}\chemname{\nousece\chemfig{[:0]*6(?(=O)-\chembelow{N}{H}-=(-CH_3)-(=O)-HN?)}}{チミン}\br{.5}
図２}

\br1


\chemnameinit{}\chemname{\nousece\chemfig{[:-138]*5(N?[a]=-N(-[:180,2] {\fbox{\parbox{1zw}{\baselineskip=0pt ＤＮＡの主鎖}}}\!)-(*6(-N=(-N(-[:-120]H)-[:0]H?[d])-N(-H?[c])-?[b](=O -[:0,1.5,,,dashed, dash pattern = on 1pt off 1pt] H -[:0] N(-[:60]H) -[:-60] *6(=N?[c,1,dashed,{dash pattern = on 1pt off 1pt}] - (=O?[d,1,dashed,{dash pattern = on 1pt off 1pt}]) - N(-[:0,2] \!{\fbox{\parbox{1zw}{\baselineskip=0pt ＤＮＡの主鎖}}}) -=-))))=?[b]?[a])}}{図４}

\br1


\chemnameinit{}\chemname{\nousece\chemfig{[:-138]*5(N?[a]=-N(-[:180,2] {\fbox{\parbox{1zw}{\baselineskip=0pt ＤＮＡの主鎖}}}\!)-(*6(-N=-N?[c]=?[b](-N(-[:120]H)-[:0]H -[:0,1.5,,,dashed, dash pattern = on 1pt off 1pt] O =[:-60] *6(-N(-H?[c,1,dashed,{dash pattern = on 1pt off 1pt}])-(=O)-N(-[:0,2] \!{\fbox{\parbox{1zw}{\baselineskip=0pt ＤＮＡの主鎖}}})-=(-CH_3)-))))=?[b]?[a])}}{図５}



\br1

\chemnameinit{}\chemname{\chemfig{CH_3 !- C(=[:60,1.2]O -[,1.65,,,dashed,{dash pattern = on 1pt off 1pt}] H?) -[:-60,1.2] O - H -[,1.65,,,dashed,{dash pattern = on 1pt off 1pt}] O=[:60,1.2]C(-[:120,1.2]O?) - CH_3}}{酢酸の二量体}

\br1

\chemnameinit{}\chemname{\bfig{[:60]*6(-(- O -[0,0.8] C(=[6,0.8]O) -[0,0.8] CH_3)=(- C(=[2,0.8]O) -[0,0.8] OH)-=-=)}}{アセチルサリチル酸}\quad\chemnameinit{}\chemname{\bfig{[:60]*6(-(- OH)=(- C(=[2,0.8]O) -[0,0.8] O -[0,0.8] CH_3)-=-=)}}{サリチル酸メチル}

\br1

\chemnameinit{}\chemname{\bfig{[,2]*6((-[1,,,,dashed,{dash pattern = on 1pt off 1pt}] ?[a](-[:-150,1.9,,,dashed,{dash pattern = on 1pt off 1pt}] O_2N) -[:-30,,,,dashed,{dash pattern = on 1pt off 1pt}] ?[b](-[:-90,1.2,,,dashed,{dash pattern = on 1pt off 1pt}] NO_2) -[:30,,,,dashed,{dash pattern = on 1pt off 1pt}] ?[c](-[:-30,1] NO_2) -[:90] ?[d](-[:30,2] NO_2) -[:150] ?[e](-[:90,1.7] NO_2) -[:-150] ?[f]?[a,,dashed,{dash pattern = on 1pt off 1pt}](-[:150,1] O_2N))(-[:-150,1.9] O_2N)-?[b,,dashed,{dash pattern = on 1pt off 1pt}](-[,1] NO_2)-?[c](-[,1] NO_2)-?[d](-[,2] NO_2)-?[e](-[,1.7] NO_2)-?[f](-[,1] O_2N)-)}}{ドデカニトロヘキサプリズマン}

\br1
\chemnameinit{}\chemname{\bfig{[:30]*6(-=(- N=*6(-=-(=N -[@{close,.5},1.6])-=-))-=-(-[@{open,.5},1.6])=)}\polymerbracket{10pt}{10pt}{n}}{アニリンブラックの主成分}

\br1
\chemnameinit{}\chemname{\cfig{H -[@{open,.5},1.6] O - CH(-[6] CH3) - C(=[2]O) -[@{close,.5},1.6] OH}\polymerbracket{18pt}{21pt}{n}}{ポリ乳酸}

\br1


{\setcrambond{3pt}{.8pt}{1pt}
\cfig{C^2(-[2,1.6]C^1)(-[:-35,1.4,1]C^3)(<:[:-170,1.6]HO)(<[:-120,1.6] {\thamidasi(1pt,-1pt){H}})}
}

\br1

{\setcrambond{3pt}{}{}
\setatomsep{2em}

\alt||<\Maru>[4]~5zw~:0zw:,0zw,{\chemfig{CH2OH -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] HO)(<[0] H) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] H)(<[0] OH) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] HO)(<[0] H) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] H)(<[0] OH) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] HO)(<[0] H) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] HO)(<[0] H) -[6] C(<[4] H)(<[0] OH) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] HO)(<[0] H) -[6] CH2OH},%
\chemfig{CH2OH -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] H)(<[0] OH) -[6] C(<[4] H)(<[0] OH) -[6] CH2OH}}}



\br1



\小見出し{ナイロン$6,6$}



\br1



{\small $n$ \ce{H2N - (CH2)6 - NH2}\ $+$\ $n$ \ce{HOOC - (CH2)4 - COOH}\ \ce{->}\ \chemfig{H -[@{open,.5},1.3] N(-[2] H) - {(}CH2{)}6 -[,1.5] N(-[2] H) - C(=[2]O) - {(}CH2{)}4 -[,1.5] C(=[2]O) -[@{close,.5},1.3] OH}\polymerbracket{20pt}{5pt}{n}\ $+$\ $(2n-1)$\ce{H2O}}


\br1


{\small $n$ \ce{H2N - (CH2)6 - NH2}\ $+$\ $n$ \ce{HOOC - (CH2)4 - COOH}\ \ce{->}\ \chemfig{-[@{open,.5},1.3] N(-[2] H) - {(}CH2{)}6 -[,1.5] N(-[2] H) - C(=[2]O) - {(}CH2{)}4 -[,1.5] C(=[2]O) -[@{close,.5},1.3]}\polymerbracket{20pt}{5pt}{n}\ $+$\ $2n$ \ce{H2O}}


\br1


\小見出し{ポリエチレンテレフタレート}

\br1

{\small $n$ \ce{HO - CH2 - CH2 - OH}\ $+$\ $n$ \ce{HOOC}\pphenyl\ce{COOH}\ \ce{->}\ \bfig{H -[@{open,.5},1] O -[,.8] CH_2 -[,.8] CH_2 -[,.8] O -[,.8] C(=[2,.8]O) - *6(-=-(- C(=[2,.8]O) -[@{close,.5},1] OH)=-=) }\polymerbracket{20pt}{10pt}{n}\ $+$\ $(2n-1)$\ce{H2O}}


\br1

{\small $n$ \ce{HO - CH2 - CH2 - OH}\ $+$\ $n$ \ce{HOOC}\pphenyl\ce{COOH}\ \ce{->}\ \bfig{-[@{open,.5},1] O -[,.8] CH_2 -[,.8] CH_2 -[,.8] O -[,.8] C(=[2,.8]O) - *6(-=-(- C(=[2,.8]O) -[@{close,.5},1])=-=) }\polymerbracket{20pt}{10pt}{n}\ $+$\ $2n$ \ce{H2O}}


\br1
%
\小見出し{ナイロン6}

\br1

$n$\ \parboxx{\chemfig{CH_2(-[:50,1.75,1] CH_2 -[,1.5] CH_2| -[:-35,1.35] N? -[:35,1.35] H)(-[:-50,1.75,1] CH_2 -[,1.5] CH_2| -[:35,1.35] C? =[:-35,1.35] O)}}\ $+$\ \ce{H2O}\ \ce{->}\ \chemfig{H -[@{open,.5},1.3] N(-[2] H) - {(}CH2{)}5 -[,1.5] C(=[2]O) -[@{close,.5},1.3] OH}\polymerbracket{20pt}{5pt}{n}

\br1

$n$\ \parboxx{\chemfig{CH_2(-[:50,1.75,1] CH_2 -[,1.5] CH_2| -[:-35,1.35] N? -[:35,1.35] H)(-[:-50,1.75,1] CH_2 -[,1.5] CH_2| -[:35,1.35] C? =[:-35,1.35] O)}}\ \ce{->}\ \chemfig{-[@{open,.5},1.3] N(-[2] H) - {(}CH2{)}5 -[,1.5] C(=[2]O) -[@{close,.5},1.3]}\polymerbracket{20pt}{5pt}{n}


\br1

\小見出し{ポリ乳酸}

\br1

$n$\ \chemfig{HO - CH(-[6] CH3) - COOH}\ \ce{->}\ \chemfig{H -[@{open,.5},1.3] O - CH(-[6] CH3) -[,1.3] C(=[2]O) -[@{close,.5},1.3] OH}\polymerbracket{20pt}{22pt}{n}\ $+$\ $(n-1)$\ce{H2O}

\br1


$n$\ \chemfig{HO - CH(-[6] CH3) - COOH}\ \ce{->}\ \chemfig{-[@{open,.5},1.3] O - CH(-[6] CH3) -[,1.3] C(=[2]O) -[@{close,.5},1.3]}\polymerbracket{20pt}{22pt}{n}\ $+$\ $n$\ce{H2O}


\br1

$n$\ \parboxx{\cfig{O? -[:-150,1.25,,2] HC(-[:150,1.25,1] H3C) -[6,1.25,2] C(=[:-150,1.25] O) -[:-30,1.25] O -[:30,1.25] CH(-[:-30,1.25] CH3) -[2,1.25] C?(=[:30,1.25] O)}}\ $+$\ \ce{H2O}\ \ce{->}\ \chemfig{H -[@{open,.5},1.3] O - CH(-[6] CH3) -[,1.3] C(=[2]O) -[@{close,.5},1.3] OH}\polymerbracket{20pt}{22pt}{2n}

\br1

$n$\ \parboxx{\cfig{O? -[:-150,1.25,,2] HC(-[:150,1.25,1] H3C) -[6,1.25,2] C(=[:-150,1.25] O) -[:-30,1.25] O -[:30,1.25] CH(-[:-30,1.25] CH3) -[2,1.25] C?(=[:30,1.25] O)}}\ \ce{->}\ \chemfig{-[@{open,.5},1.3] O - CH(-[6] CH3) -[,1.3] C(=[2]O) -[@{close,.5},1.3]}\polymerbracket{20pt}{22pt}{2n}


\br1

\小見出し{クメン法}

\[&\raisebox{-.4zw}{\bfig{*6(-=-=(- C(-[4,.9] H_3C)(-[0,.9] CH_3) -[2,.9] H)-=)}}\quad\ce{->[酸化][]}\quad\raisebox{-0.4zw}{\bfig{*6(-=-=(- C(-[4,.9] H_3C)(-[0,.9] CH_3) -[2,.9] O -[2,.9] O -[2,.9] H)-=)}}\hamidasi(-7.2zw,2.2zw)[L]{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\draw [densely dashed] (0,0) -- ++(2.35,0) -- ++(0,.41) -- ++(-.98,0) -- ++(0,.56) -- ++(-.37,0) -- ++(0,-.56) -- ++(-1,0) -- cycle;
\end{tikzpicture}}\quad\ce{->[分解][]}\quad\raisebox{-0.4zw}{\bfig{*6(-=-=(- OH)-=)}}\quad + \quad \parboxx{\cfig{H3C -[:30,1.2] C(=[2,1.2]O) -[:-30,1.2] CH3}}\]


\br1

\小見出し{電子式}

\cfig{\lewis{0:2:6:,O} -[,0.8,,,white] \lewis{0:4:,C} -[,0.8,,,white] \lewis{2:4:6:,O}}

\br{.5}
\cfig{\lewis{0:2:6:,O} -[,0.8,,,white] \lewis{2:4:6:,O}}

\br{.5}
\cfig{\lewis{0:,Na} -[,0.5,,,white] H}

\br{.5}

\cfig{H -[,0.55,,,white] \lewis{0:2:4:6:,O} -[,0.5,,,white] \lewis{0:2:6:,O} -[,0.55,,,white] H}

\br{.5}


\cfig{H -[,0.8,,,white] C(-[2,0.8,,,white] H)(-[6,0.8,,,white] H) -[,,,,white] C(=[6,0.8,,,white] O) -[,0.8,,,white] O -[,0.8,,,white] H}
\br{.08}
\hamidasi(2.3zw,1.82zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(4.8zw,1.82zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(7.17zw,1.82zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(9.4zw,1.82zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(2.97zw,.4zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(4.65zw,.4zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0,0.053) circle [radius = 0.85pt];
\fill [fill=black] (0,-0.053) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(-0.54zw,2.55zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0.053,0) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,0) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(-1.27zw,1.15zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0.053,0) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,0) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(1.3zw,1.1zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0.053,0.04) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,0.04) circle [radius = 0.85pt];
\fill [fill=black] (0.053,-0.04) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,-0.04) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(3.58zw,2.45zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0.053,0) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,0) circle [radius = 0.85pt];
\end{tikzpicture}}}
\hamidasi(2.85zw,1.2zw){\parboxx{\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\fill [fill=black] (0.053,0) circle [radius = 0.85pt];
\fill [fill=black] (-0.053,0) circle [radius = 0.85pt];
\end{tikzpicture}}}


\br1


\小見出し{夏期分野別第５問図１}

\br{.5}
{\setatomsep{2.6em}%%線の長さ指定。
\setbondoffset{2pt}
\chemnameinit{}\chemname{\parboxx{\chemfig{C\textsuperscript{\hamidasi(-1pt,5pt){7}}?(-[:150] H)=[:30] C\textsuperscript{\hamidasi(4pt,1pt){2}}(-[2] C\textsuperscript{\hamidasi(-1pt,5pt){1}}(-[:30] H)(-[:150] H)-[2] H) -[:-30] C\textsuperscript{\hamidasi(-1pt,5pt){3}}(-[:30] H)=[:-90] C\textsuperscript{\hamidasi(4pt,1pt){4}}(-[:-30] H)-[:-150] C\textsuperscript{\hamidasi(-1pt,5pt){5}}(-[6] H)=[:150] C\textsuperscript{\hamidasi(4pt,1pt){6}}?(-[:-150] H)}}}{\ajKakkoKata1}\ihspace{5zw}\chemname{\parboxx{\chemfig{C\textsuperscript{\hamidasi(4pt,1pt){6}}?(-[:-150] H) =[2] C\textsuperscript{\hamidasi(-1pt,5pt){7}}(-[:150] H)-[:30] C\textsuperscript{\hamidasi(4pt,1pt){2}}(-[2] C\textsuperscript{\hamidasi(-1pt,5pt){1}}(-[:30] H)(-[:150] H)-[2] H) =[:-30] C\textsuperscript{\hamidasi(-1pt,5pt){3}}(-[:30] H)-[:-90] C\textsuperscript{\hamidasi(4pt,1pt){4}}(-[:-30] H)=[:-150] C\textsuperscript{\hamidasi(-1pt,5pt){5}}?(-[6] H)}}}{\ajKakkoKata2}\ihspace{5zw}\chemname{\parboxx{\chemfig{C\textsuperscript{\hamidasi(-1pt,5pt){7}}?(-[:150] H)-[:30] C\textsuperscript{\hamidasi(4pt,1pt){2}}(-[2] C\textsuperscript{\hamidasi(-1pt,5pt){1}}(-[:30] H)(-[:150] H)-[2] H) -[:-30] C\textsuperscript{\hamidasi(-1pt,5pt){3}}(-[:30] H)-[:-90] C\textsuperscript{\hamidasi(4pt,1pt){4}}(-[:-30] H)-[:-150] C\textsuperscript{\hamidasi(-1pt,5pt){5}}(-[6] H)-[:150] C\textsuperscript{\hamidasi(4pt,1pt){6}}?(-[:-150] H)\text{\hamidasi(9.72zw,3.2zw){\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]\draw (0,0) circle [radius=0.55cm];\end{tikzpicture}}}}}}{\ajKakkoKata3}}



\br1


\小見出し{$\alpha$グルコース−$\beta$グルコース}

\br{.5}
{\setatomsep{1.75em}%%
\setcrambond{3pt}{}{}
\nousece\chemfig{%%% 
?[a](-[2,.8]) %
(-[:-40,1.4] O -[:40,1.4] %
?[b](-[2,.8]) %
-[:50,1.8] %
O %
-[,1.5] %
(-[2,.8])( -[6,.8,,4] HOH_2C) %
-[:-50,1.8] %
(-[2,.8] OH)(-[6,.8]) %
<[:-130,1.8] %
(-[2,.8])(-[6,.8]OH) %
-[:180,1.5,,,line width=3pt] %
?[b,{<}](-[2,.8] OH)(-[6,.8])
)
<[:-130,1.8] %
(-[2,.8])(-[6,.8]OH) %
-[:180,1.5,,,line width=3pt] %
(-[2,.8] OH)(-[6,.8]) %
>[:130,1.8] %
(-[2,.8])(-[6,.8,,2]HO) %
-[:50,1.8] %
(-[6,.8])( -[,1.5] O?[a]) %
-[2,.8] %
CH_2OH %
}
}

\br1




\小見出し{$\beta$グルコース−$\alpha$グルコース}

\br{.5}
{\setatomsep{1.75em}%%
\setcrambond{3pt}{}{}
\nousece\chemfig{%%%
?[a](-[6,.8]) %
(-[:40,1.4] O -[:-40,1.4] %
?[b](-[6,.8]) %
-[:50,1.8] %
O %
-[,1.5] %
(-[2,.8])( -[6,.8,,4] HOH_2C) %
-[:-50,1.8] %
(-[2,.8] OH)(-[6,.8]) %
<[:-130,1.8] %
(-[2,.8])(-[6,.8]OH) %
-[:180,1.5,,,line width=3pt] %
?[b,{<}](-[2,.8] OH)(-[6,.8])
)
<[:-130,1.8] %
(-[2,.8])(-[6,.8]OH) %
-[:180,1.5,,,line width=3pt] %
(-[2,.8] OH)(-[6,.8]) %
>[:130,1.8] %
(-[2,.8])(-[6,.8,,2]HO) %
-[:50,1.8] %
(-[6,.8])( -[,1.5] O?[a]) %
-[2,.8] %
CH_2OH %
}
}

\br1


\小見出し{$\beta$グルコース−$\beta$グルコース}

\br{.5}
{\setatomsep{1.75em}%%
\setcrambond{3pt}{}{}
\nousece\chemfig{%%%
?[a](-[6,.8]) %
(-[:40,1.4] O -[:-40,1.4] %
?[b](-[6,.8]) %
-[:50,1.8] %
(-[6,.8] OH)(-[2,.8]) %
-[,1.5] %
(-[2,.8] OH)( -[6,.8]) %
-[:-50,1.8] %
(-[2,.8])(-[6,.8] OH) %
<[:-130,1.8] %
(-[2,.8,,4] HOH_2C)(-[6,.8]) %
-[:180,1.5,,,line width=3pt] %
O?[b,{<}]
)
<[:-130,1.8] %
(-[2,.8])(-[6,.8]OH) %
-[:180,1.5,,,line width=3pt] %
(-[2,.8] OH)(-[6,.8]) %
>[:130,1.8] %
(-[2,.8])(-[6,.8,,2]HO) %
-[:50,1.8] %
(-[6,.8])( -[,1.5] O?[a]) %
-[2,.8] %
CH_2OH %
}
}


\br1




\小見出し{デオキシリボース}


\br{.5}

{\setatomsep{1.5em}%%
\setcrambond{2.8pt}{}{}
\setbondoffset{2pt}
\nousece\chemfig{
?[a](-[2] %塩基のほう
OH)(-[6]H) % 1位炭素
<[:-130,1.8] % 1-2結合
(-[2]H)(-[6]H) % 2位炭素
-[:180,1.5,,,line width=3pt] % 2-3結合
(-[2]H)(-[6]OH) % 3位炭素
>[:130,1.8] % 3-4結合
(-[2,,,4]HOH_2C)%リン酸のあたり
(-[6]H) % 4位炭素
-[:20,2.1]O?[a] % 4-O
}}



\br1

\小見出し{ラジカル}

\[\ce{H2O2 + e- -> OH- +}\ \lewis{4.,OH}\]

\[\ce{H2O -> }\lewis{0.,H}\ + \ \lewis{4.,OH}\]

\br1


\小見出し{$N-$\,\!アセチルノイラミン酸とタミフル}

\br{.5}
{\setatomsep{1.8em}%%線の長さ指定。chemfigじゃなきゃ効かない
\setcrambond{2.5pt}{}{}
\chemnameinit{}\chemname{\nousece\chemfig{H_3C -[:-30](=[6]O) -[::60] \chemabove{N}{H} -[::-60] <[:10,1.7](-[:-120] HO)-[:-15,1.7,,,line width=2.5pt] >[:35,1.7](-[2](=[::60]O)-[::-60]OH)(-[:-30]OH)-[:-170,1.7]O-[:165,1.7](-[4](<:[::-120]OH)-[::-60](<[::-60]OH)-[::60]-[::-60] HO)-[:-145,1.7]}}{$N-$\,\!アセチルノイラミン酸}

\br1

\chemnameinit{}\chemname{\nousece\chemfig{H_3C -[:-30](=[6]O) -[::60] \chemabove{N}{H} -[::-60] <[:10,1.7](-[:-120] H_2N)-[:-15,1.7,,,line width=2.5pt] >[:35,1.7](-[:40](=[::60]O)-[::-60]O-[::-60]-[::60])=[:-170,1.7]-[:165,1.7](-[:-170,0.9]O-[::-60](-[::-60]-[::60,.8])-[::60]-[::-60,.8])-[:-145,1.7]}}{タミフル}}
\br1


\小見出し{エチレンオキシド}


\br{.5}
\parboxx{\cfig{H2C? -[,1.3] CH2(-[:120,1.3,1,1]O?)}}

\br1


\小見出し{マレイン酸の水素結合}

\br{.5}
\cfig{C(-[5] H)(-[3] C(=[::60]O) -[::-60] O?)=C(-[7] H)-[1] C(-[::-60]OH) =[::60]O -[::40,2,,,densely dashed] H?}

\br1

\小見出し{フタル酸の水素結合}

\br{.5}
\cfig{C(-[::-120]C(=[::-60]O) -[::60] O -[::-60] H)(-[::120] H)=C(-[::-60]H) -[::60]C(=[::60]O) -[::-60]O -[::-60] H -[::0,2.5,,,densely dashed] O=[::60]C(-[::-60]O -[::-60] H) -[::60]C(-[::60] H)=C(-[::-60]H) -[::60]C(=[::60]O) -[::-60]O -[::-60] H}

\br1



\小見出し{鎖状グルコース}

\br{.5}
{\setatomsep{1.8em}%%線の長さ指定。chemfigじゃなきゃ効かない
\setcrambond{2.5pt}{}{}
\nousece\chemfig{C\textsuperscript{\hamidasi(-17pt,3pt){1}}(=[:30,1.2]O)(-[6]H) <[:165,2](-[2,0.7]H\textsuperscript{\hamidasi(-12pt,-11.5pt){2}})(-[:-55,1.1]OH) -[:-160,3,,,line width=2.5pt](-[6,.9]H\textsuperscript{\hamidasi(-12pt,10.7pt){3}})(-[:165,1.1] HO) >[:125,2.5](-[2,.9] H\textsuperscript{\hamidasi(-12pt,-15.7pt){4}})(-[:-160,1.1] HO) -[:-15,2.3](-[6,.7]H\textsuperscript{\hamidasi(-5pt,14pt){5}})(-[:125,1.1,,1] CH_2OH\textsuperscript{\hamidasi(-70pt,3pt){6}}) -[:20,2.8] OH}


\br1

%%%４位−５位間の単結合を回転
\nousece\chemfig{C\textsuperscript{\hamidasi(-17pt,3pt){1}}(=[:30,1.2]O)(-[6]H) <[:165,2](-[2,0.7]H\textsuperscript{\hamidasi(-12pt,-11.5pt){2}})(-[:-55,1.1]OH) -[:-160,3,,,line width=2.5pt](-[6,.9]H\textsuperscript{\hamidasi(-12pt,10.7pt){3}})(-[:165,1.1] HO) >[:125,2.5](-[2,.9] H\textsuperscript{\hamidasi(-12pt,-15.7pt){4}})(-[:-160,1.1] HO) -[:-15,2.3](-[6,.7]OH\textsuperscript{\hamidasi(-20pt,14pt){5}})(-[:125] H) -[:20,2.8] CH_2OH\textsuperscript{\hamidasi(-70pt,3pt){6}}}}

\br1

\小見出し{イソプレンの付加重合}
\br{.5}
\begin{tikzpicture}[x=1cm,y=1cm,>=stealth]
\draw (0,0) node [left] {\parboxx{\cfig{C(-[3] H)(-[5] H)=[,1.2]C(-[1] CH3) -[7] C(-[5] H) =[,1.2] C(-[1] H) -[7] H}}} -- ++(0.5,0);
\draw [->,>=stealth'] (0.5,0) -- ++(0,3.2) -- node [above] {\scriptsize $1,2-$\,\!付加} ++(1.5,0);
\draw (2,3.2)  node [right] {\parboxx{\cfig{-[@{open,0.1},2] C(-[2]H)(-[6]H) -[,1.2] C(-[6,2] C(-[5] H)=[,1.2] C(-[1] H)(-[7] H))(-[2] CH3) -[@{close,.57},5.5]}\polymerbracket{20.5pt}{40.5pt}{n}}};
\draw [->,>=stealth'] (0.5,0) -- node [above] {\scriptsize $3,4-$\,\!付加} ++(1.5,0);
\draw (2,0)  node [right] {\parboxx{\cfig{-[@{open,0.03},5] C(-[2,2] C(-[1] CH3)=[4,1.2] C(-[5] H)(-[3] H)) -[,1.2] C(-[2]H)(-[6]H) -[@{close,.08},2.5]}\polymerbracket{40.5pt}{20.5pt}{n}}};
\draw [->,>=stealth'] (0.5,0) -- ++(0,-3.2) -- node [above] {\scriptsize $1,4-$\,\!付加} ++(1.5,0);
\draw (2,-3.2)  node [right] {\parboxx{\cfig{-[@{open,0.1},2.5] C(-[2]H)(-[6]H) -[1,2.5] C(-[3,1.2] CH3)=[,1.2]C(-[1] H) -[7,2.5] C(-[2] H)(-[6] H) -[@{close,.08},2.5]}\polymerbracket{40.5pt}{20.5pt}{n}}\ihspace{2zw}or\ihspace{2zw}{\parboxx{\cfig{-[@{open,0.1},2.5] C(-[2]H)(-[6]H)(-[@{close,.86},9,,,white]) -[7,2.5] C(-[5,1.2] CH3)=[,1.2]C(-[1] H) -[7,2.5] C(-[2] H)(-[6] H) -[,2.5]}\polymerbracket{20.5pt}{63.7pt}{n}}}};
\end{tikzpicture}

\br1



\小見出し{組成式\ce{CH}}

\br{.5}
\ihspace{2zw}{\chemnameinit{}\chemname{\ce{H - C＃C - H}}{アセチレン\ce{C2H2}}\ihspace{8zw}\chemname{\cfig{C?(-[3] H)=[6]C(-[5] H) - C(-[7] H)=[2] C?(-[1] H)}}{シクロブタジエン\ce{C4H4}}\ihspace{8zw}\chemnameinit{}\chemname{\ce{H - C＃C - CH=CH2}}{$3-$\,\!ブテン\,\!$- 1 -$\,\!イン\ce{C4H4}\\ビニルアセチレン}

\br1
\ihspace{2zw}\chemnameinit{}\chemname{\benzene}{ベンゼン\ce{C6H6}}\ihspace{5zw}\chemname{\phenyl*{CH=CH2}}{スチレン\ce{C8H8}}\ihspace{5zw}\chemname{\cfig{C?[a](-[:165,1.9] H)(-[:50,.8] C(-[:110,1.9] H)(-[6,2] C?[d]?[e](-[:195,1.9] H)) -[,2] C?[c]?[b](-[:40,1.9] H)) -[6,2] C?[d](-[:220,1.9] H) -[,2] C(-[:-70,1.9] H)(-[:50,.8] C?[e]?[b](-[:-15,1.9] H)) -[2,2] C?[a]?[c](-[:15,1.9] H)}}{キュバン\ce{C8H8}}\ihspace{6zw}\chemnameinit{}\chemname{\pphenyl*{CH=CH2}{CH=CH2}}{\para ジビニルベンゼン\ce{C10H10}}
}


\br1

\end{document}