HOMOからLUMOへの電子遷移

\documentclass[b5j,9pt,twoside]{tetsujsarticle}
\usepackage{tetsuchem}
\pagestyle{fancy}

\begin{document}
\小見出し{HOMOからLUMOへの電子遷移}

\begin{center}
\begin{tikzpicture}
\node at (1.25,-0.5) {最も安定な電子配置};
\draw[-stealth] (0,0) -- (0,3.25);
\draw[line width=1pt] (0.5,0.5) -- (2,0.5);
\draw[line width=1pt] (0.5,1.25) -- (2,1.25);
\draw[line width=1pt] (0.5,2) -- (2,2);
\draw[line width=1pt] (0.5,2.75) -- (2,2.75);
\draw[-latex] (1.1,0.3) -- (1.1,0.7);
\draw[latex-] (1.3,0.3) -- (1.3,0.7);
\draw[-latex] (1.1,1.05) -- (1.1,1.45);
\draw[latex-] (1.3,1.05) -- (1.3,1.45);
\node[left] at (0,1.25) {ＨＯＭＯ};
\node[left] at (0,2) {ＬＵＭＯ};
\draw[->,decorate,decoration={snake,post length=0.5mm}] (2.1,1.25) -- (5.4,2) node[sloped,midway,above] {$h\nu$};
\node at (6.25,-0.5) {励起状態の電子配置};
\draw[-stealth] (5,0) -- (5,3.25);
\draw[line width=1pt] (5.5,0.5) -- (7,0.5);
\draw[line width=1pt] (5.5,1.25) -- (7,1.25);
\draw[line width=1pt] (5.5,2) -- (7,2);
\draw[line width=1pt] (5.5,2.75) -- (7,2.75);
\draw[-latex] (6.1,0.3) -- (6.1,0.7);
\draw[latex-] (6.3,0.3) -- (6.3,0.7);
\draw[-latex] (6.2,1.05) -- (6.2,1.45);
\draw[latex-] (6.2,1.8) -- (6.2,2.2);
\end{tikzpicture}
\end{center}

\br1
\小見出し{共役系化合物}

\begin{center}
\benzenefig{H_3C-[:-60](-[:60]CH_3)([:-90]*6(-[:-150]---(-[:-30]CH_3)=(-[:30]=[:-30]-[:30](-[2]CH_3)=[:-30]-[:30]=[:-30]-[:30](-[2]CH_3)=[:-30]-[:30]=[:-30]-[:30]=[:-30](-[6]CH_3)-[:30]=[:-30]-[:30]=[:-30](-[6]CH_3)-[:30]=[:-30]-[:30]?=[2](-[:150]H_3C)-[::-60]-[::-60]-[::-60]-[::-60]?(-[:-60]CH_3)(-[:-120]H_3C))-))}

\meiryo{$\beta-$\,\!カロテン}
\br1

\benzenefig{-[:30](-[2,1.14]CH_3)=[:-30]-[:30]-[:-30]-[:30](-[2,1.14]CH_3)=[:-30]-[:30]=[:-30]-[:30](-[2,1.14]CH_3)=[:-30]-[:30]=[:-30]-[:30](-[2,1.14]CH_3)=[:-30]-[:30]=[:-30]-[:30]=[:-30](-[6,1.14]CH_3)-[:30]=[:-30]-[:30]=[:-30](-[6,1.14]CH_3)-[:30]=[:-30]-[:30]=[:-30](-[6,1.14]CH_3)-[:30]-[:-30]-[:30]=[:-30](-[6,1.14]CH_3)-[:30]}

\br{0.25}
\meiryo{リコピン（トマトに含まれる赤い色素）}
\br1

\benzenefig{*6(-=(*5(-(=[::-54]O)-(=?*5(-N(-[::-54,1.4]H)-*6(-=-=-(-[:162]?(=[::-54]O))=)))-N(-[::-54,1.4]H)-))-=-=)}\ihspace{6zw}\benzenefig{*6(=-=-(-N*6(=(*6(-=(-[,1.14]NH_2)-(-[,1.14]CH_3)=-))-=N-(*6(=-=(-N(-[:150,1.4]H)-[6]*6(=-=(-CH_3)-=-))-=))--))=-)}


\br{0.25}
\meiryo{インディゴ（藍の色素）\ihspace{6zw}モーブ（人類初の合成染料）}
\br1

\benzenefig{[:18]*5(-(=[::-54]O)-O-(-[1]*6(=-=(-OH)-=-))(-[3]*6(=-=(-HO)-=-))-*6(=-=-=-))}\ce{<=>C[OH-][H+]}\benzenefig{*6(=-=(-COO)-(-[2](-[:150]*6(=-=(-[,1.4]O)-=-))=[:30]*6(-=-(=[,1.4]O)-=-))=-)}\hamidasi(-1zw,1.75zw){$^-$}\hamidasi(-17.5zw,5.5zw){$^-$}\hamidasi(-10zw,2.5zw){\tikz \draw[densely dashed,thick] (0,0) ellipse [x radius=36pt,y radius=15pt];}\hamidasi(-1zw,1.75zw)[l]{\tikz \draw[stealth-] (0,0) -- (0.5,-0.5) node[right] {\meiryo{共役が広がる}};}

\br{0.25}
\meiryo{（無色）\ihspace{10zw}（赤色）

フェノールフタレイン}
\end{center}

\br1
\小見出し{光異性化反応}

\begin{center}
\begin{tikzpicture}
\draw (0,0) -- (5,0) node[right] {\meiryo{\footnotesize 結合角}};
\draw (0.5,0.1) -- (0.5,-0.1) node[below] {\footnotesize $0\Deg$};
\draw (1.5,0.1) -- (1.5,-0.1);
\draw (2.5,0.1) -- (2.5,-0.1) node[below] {\footnotesize $90\Deg$};
\draw (3.5,0.1) -- (3.5,-0.1);
\draw (4.5,0.1) -- (4.5,-0.1) node[below] {\footnotesize $180\Deg$};
\draw[-stealth] (0,0) -- (0,3.5) node[above] {\meiryo{\footnotesize エネルギー}};
\draw[line width=1pt] (0.5,0.5) .. controls (0.75,0.5) and (1.35,1.5) .. (1.5,1.75) .. controls (1.65,2) and (2.2,3) .. (2.5,3) .. controls (2.8,3) and (3.35,2) .. (3.5,1.75) .. controls (3.65,1.5) and (4.25,0.5) .. (4.5,0.5);
\end{tikzpicture}

\br{-4.5}
\setcrambond{3pt}{}{}
\chemfig{H-[:35,1.4]C(-[:130]R)=[,1.2]C(-[:35,1.4]H)-[:-50]R}\senbun(-68,-5)(-8,-5)\senbun(-8,-5)(7,35)\senbun(7,35)(-53,35)\senbun(-53,35)(-68,-5)\ihspace{5zw}
\hamidasi(0zw,6.5zw){\chemfig{H-[:35,1.4]C(-[:130]R)=[,1.2]C(<[:70,2]H)<:[:-70,1.8]R}\senbun(-58,-2)(-3,-2)\senbun(-3,-2)(10,35)\senbun(10,35)(-45,35)\senbun(-45,35)(-58,-2)}
\ihspace{5zw}\chemfig{H-[:35,1.4]C(-[:130]R)=[,1.2]C(-[:35,1.4]R)-[:-50]H}\senbun(-68,-5)(-8,-5)\senbun(-8,-5)(7,35)\senbun(7,35)(-53,35)\senbun(-53,35)(-68,-5)
\end{center}

\br1
\begin{center}
\begin{tikzpicture}
\draw (0,0) -- (5,0) node[right] {\meiryo{\footnotesize 結合角}};
\draw (0.5,0.1) -- (0.5,-0.1) node[below] {\footnotesize $0\Deg$};
\draw (1.5,0.1) -- (1.5,-0.1);
\draw (2.5,0.1) -- (2.5,-0.1) node[below] {\footnotesize $90\Deg$};
\draw (3.5,0.1) -- (3.5,-0.1);
\draw (4.5,0.1) -- (4.5,-0.1) node[below] {\footnotesize $180\Deg$};
\draw[-stealth] (0,0) -- (0,5) node[above] {\meiryo{\footnotesize エネルギー}};
\draw[line width=1pt] (0.5,0.5) .. controls (0.75,0.5) and (1.35,1.5) .. (1.5,1.75) .. controls (1.65,2) and (2.2,3) .. (2.5,3) .. controls (2.8,3) and (3.35,2) .. (3.5,1.75) .. controls (3.65,1.5) and (4.25,0.5) .. (4.5,0.5) node[right] {\meiryo{\footnotesize 基底状態}};
\draw[line width=1pt] (0.5,4.5) .. controls (1,4.5) and (1.25,4.25) .. (1.5,4) .. controls (1.75,3.75) and (2.25,3.5) .. (2.5,3.5) .. controls (2.75,3.5) and (3.25,3.75) .. (3.5,4) .. controls (3.75,4.25) and (4,4.5) .. (4.5,4.5) node[right] {\meiryo{\footnotesize 励起状態}};
\draw[-latex,densely dotted,thick] (0.5,0.75) -- (0.5,4.25) node[midway,left] {\ajMaru1};
\draw[-latex,densely dotted,thick] (0.75,4.75) -- (2.5,3.75) node[midway,above] {\ajMaru2};
\draw[-latex,densely dotted,thick] (2.5,3.4) -- (2.5,3.1) node[midway,right] {\ajMaru3};
\draw[-latex,densely dotted,thick] (2.5,2.75) -- (1,0.5) node[midway,below,xshift=3pt] {\ajMaru4};
\draw[-latex,densely dotted,thick] (2.5,2.75) -- (4,0.5) node[midway,below,xshift=-5pt] {\ajMaru4'};
\end{tikzpicture}
\end{center}

\br1
\小見出し{蛍光}

\begin{center}
\begin{tikzpicture}[>=latex]
\draw[thick] (4,0) -- (0,0) node[left] {基底状態};
\draw[thick] (4,3) -- (0,3) node[left] {励起状態\ajRoman2};
\draw[thick] (2.5,4.5) -- (0,4.5) node[left] {励起状態\ajRoman1};
\draw[->,very thick] (0.6,0) -- (0.6,4.5) node[midway,left] {\small 光の吸収 $h\nu$};
\draw[->,decorate,decoration={snake,amplitude=0.4mm,segment length=2mm,post length=1mm}] (1.2,4.5) -- (1.2,3) node[midway,right] {\small 熱の放出};
\draw[->,decorate,decoration={snake,amplitude=0.4mm,segment length=2mm,post length=1mm}] (1.9,3) --  (1.9,0) node[midway,fill=white,draw,yshift=5mm] {\small \ajMaru1熱の放出};
\draw[->,very thick] (3.3,3) -- (3.3,0) node[midway,fill=white,draw,yshift=-5mm] {\small \ajMaru2光の放出 $h\nu'$};
\node[right,single arrow,draw,rotate=-30] at (4,3) {\small \ajMaru3化学反応};
\end{tikzpicture}
\end{center}

\小小見出し{蛍光増白剤}

\begin{center}
\benzenefig{[:30]*6(=(-SO_3Na)-(-CH=[,1.4]CH-*6(=-=(-CH=[,1.4]CH-*6(=-=-=(-[,,,3]NaO_3S)-))-=-))=-=-)}
\end{center}

\br1
\小見出し{ルミノール反応}

\begin{center}
$\underset{\meiryo{ルミノール}}{\benzenefig{*6(=-(-C(=[6,1.4]O)-[:15,1.4]N?(-[:-30,1.4]H))=(-C(=[2,1.4]O)-[:-15,1.4]N?(-[:30,1.4]H))-(-[,,,2]H_2N)=-)}}$\quad\ce{->C[OH-]}\quad
\benzenefig{*6(=-(-C(=[6,1.4]O)-[:15,1.4]N?{\hamidasi(0zw,0zw)[l]{${}^-$}})=(-C(=[2,1.4]O)-[:-15,1.4]N?{\hamidasi(0zw,0zw)[l]{${}^-$}})-(-[,,,2]H_2N)=-)}\quad\ce{->C[H2O2]}\quad
\benzenefig{*6(=-(-C(=[6,1.4]O)-[:15,1.4]N?{\hamidasi(0zw,0zw)[l]{${}^-$}})=(-C(=[2,1.4]O)-[:-15,1.4]N?-[:30,1.4]O-[0,1.4]O{\hamidasi(0zw,0zw)[l]{${}^-$}})-(-[,,,2]H_2N)=-)}\quad\cto\quad
$\underset{\meiryo{\small （励起状態）}}{\benzenefig{*6(=-(-C(=[6,1.4]O)-[:15,1.4]O{\hamidasi(0zw,0zw)[l]{${}^-$}})=(-C(=[2,1.4]O)-[:-15,1.4]O{\hamidasi(0zw,0zw)[l]{${}^-$}})-(-[,,,2]H_2N)=-)}}\quad + \ce{N2}$
\end{center}


\br1
\小見出し{ホタルルシフェリンの発光}

\begin{center}
\raisebox{-1zw}{\benzenefig{HO-[:30,1.2]*6(-=(*5(-S-(-*5(-S--(-[0,1.2]COOH)(-[2,1.2]H)-N=))=N-))-=-=)}}\quad\ce{->C[\meiryo{\footnotesize 酵素}]}\quad
\raisebox{-1zw}{\benzenefig{HO-[:30,1.2]*6(-=(*5(-S-(-*5(-S--(?-[0,1.2](=[:-45,1.2]O)-[2,1.2]O-[4,1.2]O?)-N=))=N-))-=-=)}}\quad\cto\quad
\raisebox{-1zw}{$\underset{\meiryo{\small （励起状態）}}{\benzenefig{O-[:30,1.2]*6(-=(*5(-S-(-*5(-S--(=[,1.2]O)-N=))=N-))-=-=)}}$}\ce{ + CO2}
\end{center}


\br1
\小見出し{分光学}

\begin{center}
\begin{tikzpicture}
\draw[->] (0,0) -- (12,0) node[right] {波長\〔\m〕};
\draw (0,0.1) -- (0,-0.1) node[below] {\footnotesize $10^{-13}$};
\draw (0.75,0.1) -- (0.75,-0.1) node[below] {\footnotesize $10^{-12}$};
\draw (1.5,0.1) -- (1.5,-0.1) node[below] {\footnotesize $10^{-11}$};
\draw (2.25,0.1) -- (2.25,-0.1) node[below] {\footnotesize $10^{-10}$};
\draw (3,0.1) -- (3,-0.1) node[below] {\footnotesize $10^{-9}$};
\draw (3.75,0.1) -- (3.75,-0.1) node[below] {\footnotesize $10^{-8}$};
\draw (4.5,0.1) -- (4.5,-0.1) node[below] {\footnotesize $10^{-7}$};
\draw (5.25,0.1) -- (5.25,-0.1) node[below] {\footnotesize $10^{-6}$};
\draw (6,0.1) -- (6,-0.1) node[below] {\footnotesize $10^{-5}$};
\draw (6.75,0.1) -- (6.75,-0.1) node[below] {\footnotesize $10^{-4}$};
\draw (7.5,0.1) -- (7.5,-0.1) node[below] {\footnotesize $10^{-3}$};
\draw (8.25,0.1) -- (8.25,-0.1) node[below] {\footnotesize $10^{-2}$};
\draw (9,0.1) -- (9,-0.1) node[below] {\footnotesize $10^{-1}$};
\draw (9.75,0.1) -- (9.75,-0.1) node[below] {\footnotesize $10^{0}$};
\draw (10.5,0.1) -- (10.5,-0.1) node[below] {\footnotesize $10^{1}$};
\draw (11.25,0.1) -- (11.25,-0.1) node[below] {\footnotesize $10^{2}$};
\draw (0,0.25) -- (12,0.25);
\draw (0,1) -- (12,1);
\draw (1.6,0.25) -- (2.8,1);
\draw (3.9,0.25) -- (3.9,1);
\draw (4.65,0.25) -- (4.65,1);
\draw (5.1,0.25) -- (5.1,1);
\draw (7.5,0.25) -- (7.5,1);
\draw (9.5,0.25) -- (9.5,1);
\node at (1.1,0.625) {\footnotesize $\gamma$線};
\node at (3.05,0.625) {\footnotesize X線};
\node at (4.275,0.425) {\footnotesize 紫外線};
\node at (4.875,0.825) {\footnotesize 可視光線};
\node at (6.3,0.625) {\footnotesize 赤外線};
\node at (8.5,0.625) {\footnotesize マイクロ波};
\node at (10.75,0.625) {\footnotesize 電波};
\draw[thick,decorate,decoration=brace] (2.8,1.25) -- (4.875,1.25) node[midway,above] {電子遷移};
\draw[thick,decorate,decoration=brace] (5.25,1.25) -- (6.75,1.25) node[midway,above] {\fbox{振動遷移}};
\draw[thick,decorate,decoration=brace] (7,1.25) -- (8.25,1.25) node[midway,above] {回転遷移};
\draw[thick,decorate,decoration=brace] (8.5,1.25) -- (10.5,1.25) node[midway,above] {磁気共鳴};
\node[above,right] at (-0.25,1.5) {分子との相互作用：};
\end{tikzpicture}
\end{center}


\br1
\小見出し{\ce{H2O}の分子振動}

\begin{center}
\begin{tikzpicture}
\draw[line width=2mm] (0,0) -- (1.04,0.6) -- (2.08,0);
\draw[fill=white] (0,0) circle (0.3cm);
\draw[fill=gray] (1.04,0.6) circle (0.5cm);
\draw[fill=white] (2.08,0) circle (0.3cm);
\node[single arrow,right,draw,rotate=90,scale=0.5] at (1.04,1.25) {\makebox[3zw][l]{}};
\node[single arrow,right,draw,rotate=210,scale=0.5] at (-0.35,-0.2) {\makebox[3zw][l]{}};
\node[single arrow,right,draw,rotate=-30,scale=0.5] at (2.43,-0.2) {\makebox[3zw][l]{}};
\end{tikzpicture}\ihspace{3zw}
\begin{tikzpicture}
\draw[line width=2mm] (0,0) -- (1.04,0.6) -- (2.08,0);
\draw[fill=white] (0,0) circle (0.3cm);
\draw[fill=gray] (1.04,0.6) circle (0.5cm);
\draw[fill=white] (2.08,0) circle (0.3cm);
\node[single arrow,right,draw,rotate=90,scale=0.5] at (1.04,1.25) {\makebox[3zw][l]{}};
\node[single arrow,right,draw,rotate=-30,scale=0.5] at (0.3,-0.3) {\makebox[3zw][l]{}};
\node[single arrow,right,draw,rotate=210,scale=0.5] at (1.78,-0.3) {\makebox[3zw][l]{}};
\end{tikzpicture}\ihspace{3zw}
\begin{tikzpicture}
\draw[line width=2mm] (0,0) -- (1.04,0.6) -- (2.08,0);
\draw[fill=white] (0,0) circle (0.3cm);
\draw[fill=gray] (1.04,0.6) circle (0.5cm);
\draw[fill=white] (2.08,0) circle (0.3cm);
\node[single arrow,right,draw,scale=0.5] at (1.54,1.1) {\makebox[3zw][l]{}};
\node[single arrow,right,draw,rotate=210,scale=0.5] at (-0.35,-0.2) {\makebox[3zw][l]{}};
\node[single arrow,left,draw,rotate=150,scale=0.5] at (2.43,-0.2) {\makebox[3zw][l]{}};
\end{tikzpicture}
\end{center}

\br1
\小見出し{レーザーの原理}
\begin{center}
\begin{tikzpicture}[>=latex]
\draw[thick] (0,0) -- (2.5,0) node[midway,below] {基底状態};
\draw[thick] (2.5,3) -- (0,3) node[left] {Ｒ線};
\node[left] at (0,4) {Ｕ帯};
\filldraw[fill=black!25!white,draw=black!25!white] (0,3.5) -- (2.5,3.5) -- (2.5,4.5) -- (0,4.5) --cycle;
\draw[thick] (0,3.5) -- (2.5,3.5);
\draw[thick] (0,4.5) -- (2.5,4.5);
\draw[->,thick] (0.75,0) -- (0.75,4) node[midway,left] {\footnotesize 励起};
\draw[->,decorate,decoration={snake,amplitude=0.6mm,segment length=0.6mm,post length=1.8mm}] (1.75,3.5) -- (1.75,3) node[midway,right] {\footnotesize 非放射遷移（光の放出を伴わない）};
\node[single arrow,draw,right,rotate=-90] at (1.75,3) {\makebox[8zw][l]{}};
\draw[->,decorate,decoration={snake,amplitude=2mm,segment length=2mm,post length=2mm}] (1.88,1.5) -- (3,1.5) node at +(0,-0.35) {\footnotesize レーザー};
\end{tikzpicture}
\end{center}

\br1
\小見出し{マインドマップ的まとめ}

\begin{tikzpicture}
\path[mindmap,every node/.style=concept,concept color=black!35!white,grow cyclic]
 node {光機能性}
  child{
  node {光→化学反応}
   child {node {有用／有害物質の合成}}
   child {node {光重合}}
   child {node {光異性化}}
 }
  child{
  node {化学反応→光}
   child {node {燃焼}}
   child {node {化学発光}}
   child {node {生物発光}}
 }
  child{
  node {熱→光}
   child {node {黒体放射}}
 }
  child{
  node {光→光}
   child {node {光吸収}}
   child {node {発光}}
   child {node {偏光}}
 }
  child{
  node {電気→光}
   child {node {ＬＥＤ}}
   child {node {放電管}}
   child {node {レーザー}}
 }
  child{
  node {光→熱}
   child {node {光ディスク}}
   child {node {レーザー治療}}
 };
\end{tikzpicture}

\end{document}