ChemZサンプル

\documentclass[b5j,10pt,twoside]{tetsujsarticle}
\usepackage{tetsuchem}
\pagestyle{empty}% empty にするとヘッダ・フッタ類が全部消える

\余白設定[% デフォルトでは一行字数を四捨五入により整数zwに調整する。\余白設定* だと一行字数を切り上げで整数zwに調整，\余白設定** だと調整しない。
上余白=1truecm,
下余白=上余白,
左余白=1.414truecm,
左右差=0truecm,
段間隔=4zw,% B4横を2段組にしてB5縦を2枚並べたように見せるときには 段間隔=対称 とする。
段組の仕切り線の太さ=.5truept,
ヘッダの縦幅=16truept,
ヘッダ下端と本文上端の縦間隔=10truept,
ヘッダと本文を仕切る線の太さ=0truept,
本文下端とフッタ下端の縦間隔=20truept,
本文とフッタを仕切る線の太さ=0truept,
傍注領域の幅=0zw,
本文端と傍注領域との間隔=0truept,
傍注同士の縦間隔=\baselineskip,
奇数ページの傍注位置=右,
偶数ページの傍注位置=左,
]
%\段間隔調整{n}% n段組にしたときに一行字数が整数になるよう適切な段間隔に調整する。デフォルトでは現在の一行字数に最も近い字数に調整するが，\段間隔調整* だと一行字数を切り上げで整数zwに調整する。\段間隔調整** だと調整しない。

\fancyhead[OR]{\footnotesize\gtfamily 奇数ページヘッダ右上}
\fancyhead[EL]{\footnotesize\gtfamily 偶数ページヘッダ左上}
\fancyfoot[C]{−\arabic{page}−} % 中央フッタにページ番号

%%% This sample is written by Y. Sata.

\begin{document}

\begin{center}

\setcrambond{3pt}{}{}

\noindent \hfil\chemname{\benzenefig{*6(-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]COOH)(<[:-60,1.5]NH_2)<:[0,1.5]H)-=-(-[:150,1.4]HO)=)}}{\Lhyphen チロシン\\ （分子量 181）}\ce{->[][反応１]}\chemname{\benzenefig{*6((-[:210,1.4]X^1)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]COOH)(<[:-60,1.5]NH_2)<:[0,1.5]H)-=(-[2,1.4]X|^1)-(-[:150,1.4]HO)=)}}{化合物\bf{A}}\ce{->[][反応２]}\chemname{\benzenefig{*6((-[:210,1.4]X^1)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]COOH)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]X|^1)-(-[:150,1.4]HO)=)}}{化合物\bf{B}}

\br{1}

\noindent \hfil\ce{->[][反応３]}\chemname{\benzenefig{*6((-[:210,1.4]X^1)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]C(=[0,1.4]O)-[:120,1.4]O-[:60,1.4]CH_2-[:120,1.4]H_3C)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]X|^1)-(-[:150,1.4]HO)=)}}{化合物\bf{C}}\ce{->[][反応４]}\chemname{\benzenefig{*6((-[:210,1.4]O-[:-90,1.4]CH_3)-=-(-[:30,1.4]O(-[:-30,1.4]*6(=(-[:210,1.4]X^1)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]C(=[0,1.4]O)-[:120,1.4]O-[:60,1.4]CH_2-[:120,1.4]H_3C)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]X|^1)-)))=-=)}}{化合物\bf{D}}\ce{->[][反応５]}

\br{1}

\noindent \hfil\chemname{\benzenefig{*6((-[:210,1.4]O-[:-90,1.4]CH_3)-=-(-[:30,1.4]O(-[:-30,1.4]*6(=(-[:210,1.4]X^2)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]C(=[0,1.4]O)-[:120,1.4]O-[:60,1.4]CH_2-[:120,1.4]H_3C)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]X|^2)-)))=-=)}}{化合物\bf{E}}\ce{->[][反応６]}\chemname{\benzenefig{*6((-[:210,1.4]O-[:-90,1.4]CH_3)-=-(-[:30,1.4]O(-[:-30,1.4]*6(=(-[:210,1.4]X^3)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]C(=[0,1.4]O)-[:120,1.4]O-[:60,1.4]CH_2-[:120,1.4]H_3C)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]X|^3)-)))=-=)}}{化合物\bf{F}}\ce{->[\ce{NaI},\ce{I2}][反応７]}

\br{1}

\noindent \hfil\chemname{\benzenefig{*6((-[:210,1.4]O-[:-90,1.4]CH_3)-=-(-[:30,1.4]O(-[:-30,1.4]*6(=(-[:210,1.4]I)-=(-[:-30,1.4]CH_2-[0,1.5](-[:60,1.4]C(=[0,1.4]O)-[:120,1.4]O-[:60,1.4]CH_2-[:120,1.4]H_3C)(<[:-60,1.5]NH-[:-90,1.4]C(=[:210,1.4]O)-[:-30,1.4]CH_3)<:[0,1.5]H)-=(-[2,1.4]I)-)))=-=)}}{化合物\bf{G}}\ce{->[][反応８] ->[][反応９]}\chemname{\benzenefig{*6((-[:210,1.3]HO)-(-[:-90,1.3]I)=-(-[:30,1.3]O(-[:-30,1.3]*6(=(-[:210,1.3]I)-=(-[:-30,1.3]CH_2-[0,1.4](-[:60,1.3]COOH)(<:[0,1.5]H)(<[:-60,1.5]NH_2))-=(-[:90,1.3]I)-)))=-(-[:150,1.3]I)=)}}{\Lhyphen チロキシン\\ （分子量 777）}

\br{1}

\chemname[-1zw]{\benzenefig{*6((-[:210,1.3]HO)-(-[:-90,1.3]I)=-(-[:30,1.3]O(-[:-30,1.3]*6(=(-[:210,1.3]I)-=(-[:-30,1.3]CH_2-[0,1.4](-[:60,1.3]NH_2)(<:[0,1.5]COOH)(<[:-60,1.5]H))-=(-[:90,1.3]I)-)))=-(-[:150,1.3]I)=)}}{\ajKakko{1}}\hspace{5zw}\chemname[-1zw]{\benzenefig{*6((-[:210,1.3]HO)-(-[:-90,1.3]I)=-(-[:30,1.3]O(-[:-30,1.3]*6(=(-[:210,1.3]I)-=(-[:-30,1.3]CH_2-[0,1.4](-[:60,1.3]H)(<:[0,1.5]NH_2)(<[:-60,1.5]COOH))-=(-[:90,1.3]I)-)))=-(-[:150,1.3]I)=)}}{\ajKakko{2}}

\br{1}

\chemname[-1zw]{\benzenefig{*6((-[:210,1.3]I)-=(-[:-30,1.3]O(-[:30,1.3]*6(-(-[:-90,1.3]I)=-(-[:30,1.3]CH_2-[0,1.4](-[:60,1.3]NH_2)(<:[0,1.5]COOH)(<[:-60,1.5]H))=-(-[:150,1.3]I)=)))-=(-[2,1.3]I)-(-[:150,1.3]HO)=)}}{\ajKakko{3}}\hspace{5zw}\chemname[-1zw]{\benzenefig{*6((-[:210,1.3]I)-=(-[:-30,1.3]O(-[:30,1.3]*6(-(-[:-90,1.3]I)=-(-[:30,1.3]CH_2-[0,1.4](-[:60,1.3]H)(<:[0,1.5]COOH)(<[:-60,1.5]NH_2))=-(-[:150,1.3]I)=)))-=(-[2,1.3]I)-(-[:150,1.3]HO)=)}}{\ajKakko{4}}

\br{1}

\chemname[-1zw]{\benzenefig{*6((-[:210,1.3]I)-=(-[:-30,1.3]O(-[:30,1.3]*6(-(-[:-90,1.3]I)=-(-[:30,1.3]CH_2-[0,1.4](-[:60,1.3]COOH)(<:[0,1.5]H)(<[:-60,1.5]NH_2))=-(-[:150,1.3]I)=)))-=(-[2,1.3]I)-(-[:150,1.3]HO)=)}}{\ajKakko{5}}\hspace{5zw}\chemname[-1zw]{\benzenefig{*6(=(-[:-90,1.3]I)-(-[:-30,1.3]O(-[:30,1.3]*6(=-(-[:-30,1.3]I)=(-[:30]OH)-(-[2,1.3]I)=-)))=(-[:30,1.3]I)-=(-[:150,1.4]CH_2-[4,1.3](<[:120,1.5]HOOC)(<:[4,1.5]H_2N)-[:-120,1.3]H)-)}}{\ajKakko{6}}

\br{1}

\chemname[-1zw]{\benzenefig{*6(=(-[:-90,1.3]I)-(-[:-30,1.3]O(-[:30,1.3]*6(=-(-[:-30,1.3]I)=(-[:30]OH)-(-[2,1.3]I)=-)))=(-[:30,1.3]I)-=(-[:150,1.4]CH_2-[4,1.3](<[:120,1.5]H)(<:[4,1.5]HOOC)-[:-120,1.3]H_2N)-)}}{\ajKakko{7}}\hspace{5zw}\chemname[-1zw]{\benzenefig{*6((-[:210,1.4]CH_2-[4,1.3](-[:120,1.5]H)(<:[4,1.5]HOOC)<[:-120,1.3]H_2N)=-(-[:-30,1.3]I)=(-[:30,1.3]O(-[:-30,1.3]*6(=-(-[:-90,1.3]I)=(-[:-30]OH)-(-[:30,1.3]I)=-)))-(-[2,1.3]I)=-)}}{\ajKakko{8}}

\br{1}

\begin{tikzpicture}
\node[rectangle,draw] (c0) at (2.5,0) {セレブロシド};
\node[rectangle,draw] (l1) at (1,-2) {\gt{T1}};
\node[rectangle,draw] (r1) at (4,-2) {\gt{N1}};
\node[rectangle,draw] (l2) at (0,-4) {\gt{T2}};
\node[rectangle,draw] (r2) at (2,-4) {\gt{N2}};
\coordinate (T1の上) at ($(l1)+(0,0.7)$);
\coordinate (N1の上) at ($(r1)+(0,0.7)$);
\coordinate (中間1) at ($ (T1の上)!.5!(N1の上) $);
\draw [<-,shorten <=1pt,>=stealth',semithick] (l1) -- (T1の上);
\draw [<-,shorten <=1pt,>=stealth',semithick] (r1) -- (N1の上);
\draw (T1の上) -- (N1の上);
\draw (中間1) -- (c0);
\coordinate (T2の上) at ($(l2)+(0,0.7)$);
\coordinate (N2の上) at ($(r2)+(0,0.7)$);
\coordinate (中間2) at ($ (T2の上)!.5!(N2の上) $);
\draw [<-,shorten <=1pt,>=stealth',semithick] (l2) -- (T2の上);
\draw [<-,shorten <=1pt,>=stealth',semithick] (r2) -- (N2の上);
\draw (T2の上) -- (N2の上);
\draw (中間2) -- (l1);
\draw (5.5,-0.7) node {酵素反応１：アミド結合を加水分解する};
\draw (4.7,-2.9) node {酵素反応２：\parbox[t]{16zw}{$\beta-$\!\,ガラクトース部分を認識して，\\ そのグリコシド結合を加水分解する}};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\node (A) at (0,0) {\bf{A}};
\node (B) at (2,0) {\bf{B}};
\node (E) at ($(B)+(0,-1.2)$) {\bf{E}};
\node (M1) at (4,0) {\bf{M1}};
\node (M2) at ($(M1)+(0,-1.2)$) {\bf{M2}};
\draw [->,>=stealth'] (A) -- node [anchor=south] {\ce{KMnO4}} (B);
\draw [->,>=stealth'] (E) -- node [anchor=south] {\ce{Fe}} (M2);
\draw [->,>=stealth'] (B) -- (M1);
\draw [->,>=stealth'] (B) .. controls ($(B)!.5!(M1)$) .. ($(B)!.5!(M1)+(0,0.5)$) node[anchor=south,rectangle] {\ce{H2O}};
\coordinate (M1の右) at ($(M1)+(1,0)$);
\coordinate (M2の右) at ($(M2)+(1,0)$);
\coordinate (M1とM2の間) at ($(M1の右)!.5!(M2の右)$);
\draw (M1) -- (M1の右) -- (M2の右) -- (M2);
\draw [->,>=stealth'] (M1とM2の間) -- ($(M1とM2の間)+(1.5,0)$) node [anchor=west] (P) {\bf{P}};
\draw [->,>=stealth'] (M1とM2の間) .. controls ($(M1とM2の間)!.5!(P)$) .. ($(M1とM2の間)!.5!(P)+(0,0.5)$) node[anchor=south,rectangle] {\ce{H2O}};
\coordinate (M1の上) at ($(M1)+(0,1)$);
\draw (M1) -- (M1の上);
\draw [->,>=stealth'] (M1の上) -- node[anchor=south] {\ce{CH3CH2OH}} ($(M1の上)+(2,0)$) node[anchor=west] {\bf{C}＋\bf{D}};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}[scale=0.7]
\draw (0,0) rectangle (12,8.8);
\foreach \x/\xtext in {0/0.0,3/2.0,6/4.0,9/6.0,12/8.0} \draw (\x cm,0pt) -- node [below=0.3cm] {$\xtext$} (\x cm,7pt);
\foreach \y/\ytext in {0/1.300,2/1.305,4/1.310,6/1.315,8/1.320} \draw (0pt,\y cm) node [left=0.1cm] {$\ytext$} -- (12cm,\y cm);
\foreach \yy in {0.4,0.8,1.2,1.6,2.4,2.8,3.2,3.6,4.4,4.8,5.2,5.6,6.4,6.8,7.2,7.6,8.4} \draw (0pt,\yy cm) -- (7pt,\yy cm);
\draw [dashed] (0,7.6) -- (12,7.6);
\node at ($(0,-1.5)!.5!(12,-1.5)$) {時間$\〔\times 10^{-7}\,\s〕$};
\node at ($(-2,0)!.5!(-2,8.8)$) {\rotatebox{90}{$[\ce{OH-}] \〔\times 10^{-4}\,\mol\cdot\L^{-1}〕$}};
\draw [very thick] (0,0.8) .. controls (1.5,7.6) and (3,7.6) .. (12,7.6);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}[scale=0.75]
\draw (0,0) rectangle (12,10);
\foreach \x/\xtext in {0/-2.0,3/-1.5,6/-1.0,9/-0.5,12/0.0} \draw (\x cm,0pt) node [below=0.3cm] {$\xtext$} -- (\x cm,10);
\foreach \y/\ytext in {0/0.0,2/5.0,4/10.0,6/15.0,8/20.0,10/25.0} \draw (0pt,\y cm) node [left=0.1cm] {$\ytext$} -- (12cm,\y cm);
\foreach \yy in {0.4,0.8,1.2,1.6,2.4,2.8,3.2,3.6,4.4,4.8,5.2,5.6,6.4,6.8,7.2,7.6,8.4,8.8,9.2,9.6} \draw (0pt,\yy cm) -- (7pt,\yy cm);
\node at ($(0,-1.5)!.5!(12,-1.5)$) {$x \〔\times 10^{-6}\,\mol\cdot\L^{-1}〕$};
\node at ($(-1.7,0)!.5!(-1.7,10)$) {\rotatebox{90}{$\varDelta[\ce{OH-}]/\varDelta t \〔\mol\cdot\L^{-1}\cdot\s^{-1}〕$}};
\draw [very thick] (0,8.8) -- (12,0);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\coordinate (左下) at (0,0);
\coordinate (右下) at (7,0);
\coordinate (左上) at (0,4.5);
\coordinate (右上) at (7,4.5);
\coordinate (上の中点) at ($(左上)!.5!(右上)$);
\coordinate (下の中点) at ($(左下)!.5!(右下)$);
\draw ($(左下)+(-1,0.5)$) -- ($(左下)+(0,0.5)$) -- (左下) -- (右下) -- ($(右下)+(0,0.5)$) -- ($(右下)+(1,0.5)$);
\draw ($(左上)+(-1,-0.7)$) -- ($(左上)+(0,-0.7)$) -- (左上) -- ($(左上)!.5!(上の中点)+(-0.25,0)$) -- ($(左上)!.5!(上の中点)+(-0.25,1)$);
\draw ($(左上)!.5!(上の中点)+(+0.25,1)$) -- ($(左上)!.5!(上の中点)+(+0.25,0)$) -- ($(上の中点)!.5!(右上)+(-0.25,0)$) -- ($(上の中点)!.5!(右上)+(-0.25,1)$);
\draw ($(上の中点)!.5!(右上)+(+0.25,1)$) -- ($(上の中点)!.5!(右上)+(+0.25,0)$) -- (右上) -- ($(右上)+(0,-0.7)$) -- ($(右上)+(1,-0.7)$);
\draw ($(左上)+(-1,-1.2)$) -- ($(左上)+(0,-1.2)$) -- ($(左下)+(0,1)$) -- ($(左下)+(-1,1)$);
\draw ($(右上)+(1,-1.2)$) -- ($(右上)+(0,-1.2)$) -- ($(右下)+(0,1)$) -- ($(右下)+(1,1)$);
\draw [dashed] (上の中点) -- (下の中点);
\draw ($(左上)+(0,-0.5)$) -- ($(右上)+(0,-0.5)$);
\draw [->,>=stealth'] ($(左上)+(-0.7,-0.95)$) -- ($(左上)+(-1.7,-0.95)$);
\node at ($(左上)+(-1.7,-0.95)+(0,0.5)$) {流出液};
\draw [->,>=stealth'] ($(左下)+(-1.7,0.75)$) -- ($(左下)+(-0.7,0.75)$);
\node at ($(左下)+(-1.7,0.75)+(-0.3,0.5)$) {飽和食塩水};
\draw [->,>=stealth'] ($(右上)+(0.7,-0.95)$) -- ($(右上)+(1.7,-0.95)$);
\node at ($(右上)+(1.7,-0.95)+(0,0.5)$) {流出液};
\draw [->,>=stealth'] ($(右下)+(+1.7,0.75)$) -- ($(右下)+(0.7,0.75)$);
\node at ($(右下)+(1,0.75)+(0.3,0.5)$) {水};
\draw [->,>=stealth'] ($(左上)!.5!(上の中点)+(0,0.5)$) -- ($(左上)!.5!(上の中点)+(0,1.2)$);
\node at ($(左上)!.5!(上の中点)+(0,1.7)$) {気　体};
\draw [->,>=stealth'] ($(上の中点)!.5!(右上)+(0,0.5)$) -- ($(上の中点)!.5!(右上)+(0,1.2)$);
\node at ($(上の中点)!.5!(右上)+(0,1.7)$) {気　体};
\draw [very thick,fill=black!70!white] ($(左下)+(0.3,1.2)$) rectangle node [right=0.2] {\mbox{\tate 陽　極}} ($(左上)+(0.7,-1.4)$) ;
\draw [very thick,fill=black!70!white] ($(右下)+(-0.3,1.2)$) rectangle node [left=0.2] {\mbox{\tate 陰　極}} ($(右上)+(-0.7,-1.4)$);
\node [scale=1.2] (プラス) at ($(左上)!.5!(左下)+(-1.2,-0.1)$) [circle,draw,inner sep=-2pt] {＋};
\draw [ultra thick] (プラス) -- ($(左上)!.5!(左下)+(0.3,-0.1)$);
\node [scale=1.2] (マイナス) at ($(右上)!.5!(右下)+(1.2,-0.1)$) [circle,draw,inner sep=-2pt] {−};
\draw [ultra thick] (マイナス) -- ($(右上)!.5!(右下)+(-0.3,-0.1)$);
\node at ($(下の中点)+(-1.2,0.7)$) {陽極室};
\node at ($(下の中点)+(1.2,0.7)$) {陰極室};
\node (下の説明) at ($(下の中点)+(-1,-0.7)$) {隔膜もしくはイオン交換膜};
\draw (下の説明) -- ($(下の中点)+(-0.2,0.4)$);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\node at (0,0) {図２　実験装置};
\draw (0,1.5) circle [radius=1];
\coordinate (容器１の中心) at (0,1.5);
\node at ($(容器１の中心)+(0.05,0.725)$) {容器\ajRoman{1}};
\fill [black] (0,0.7) circle [radius=0.2];
\fill [black] (0.3,0.75) circle [radius=0.2];
\fill [black] (-0.3,0.75) circle [radius=0.2];
\fill [black] (0.17,1.05) circle [radius=0.2];
\fill [black] (-0.17,1.05) circle [radius=0.2];
\node (シリカゲル試料) at (2,2.25) {シリカゲル試料};
\draw [->,>=stealth'] (シリカゲル試料) -- (0.4,1.25);
\coordinate (容器２の中心) at ($(容器１の中心)+(0,3)$);
\draw (容器２の中心) circle [radius=1];
\node at ($(容器２の中心)+(0.05,0.725)$) {容器\ajRoman{2}};
\coordinate (弁A) at ($(容器１の中心)!.5!(容器２の中心)$);
\draw ($(弁A)+(-0.15,-0.15)$) -- ++(0.3,0) -- ++(-0.3,0.3) -- ++(0.3,0) -- cycle;
\node at ($(弁A)+(0.6,0)$) {弁A};
\draw [ultra thick] ($(容器１の中心)+(0,1)$) -- ($(弁A)+(0,-0.15)$);
\draw [ultra thick] ($(弁A)+(0,+0.15)$) -- ($(容器２の中心)+(0,-1)$);
\coordinate (弁Bの上) at ($(容器２の中心)+(0,3)$);
\coordinate (弁B) at ($(容器２の中心)!.5!(弁Bの上)$);
\draw ($(弁B)+(-0.15,-0.15)$) -- ++(0.3,0) -- ++(-0.3,0.3) -- ++(0.3,0) -- cycle;
\node at ($(弁B)+(0.6,0)$) {弁B};
\draw [ultra thick] ($(容器２の中心)+(0,1)$) -- ($(弁B)+(0,-0.15)$);
\draw [ultra thick] ($(弁B)+(0,+0.15)$) -- ($(弁Bの上)+(0,-1)$);
\draw [->,>=stealth'] ($(弁Bの上)+(0.1,0.2)$) -- +(0,-1);
\draw [->,>=stealth'] ($(弁Bの上)+(-0.1,-0.8)$) -- +(0,+1);
\node at ($(弁Bの上)+(1.1,-0.3)$) {\parbox{5zw}{\baselineskip=10pt 気体の導入および排気}};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\draw [->,>=stealth,thick] (0,0) -- (12,0) node [below=10pt,anchor=east] {反応の方向};
\draw [->,>=stealth,thick] (0,0) -- node [left=5pt] {\mbox{\tate エネルギー}} (0,5);
\coordinate (反応物) at (1.5,1.5);
\coordinate (生成物) at (11,0.5);
\coordinate (活性化状態１) at (5,4.5);
\coordinate (反応中間体) at (6.5,3);
\coordinate (活性化状態２) at (8,3.75);
\draw [dashed] (反応物) -- +(7,0) coordinate (上の線);
\draw [dashed] (生成物) -- +(-9,0) coordinate (下の線);
\draw [thick] (反応物) .. controls +(2,0) and +(-0.7,0) .. (活性化状態１) .. controls +(0.7,0) and +(-0.7,0) .. (反応中間体) .. controls +(0.7,0) and +(-0.7,0) .. (活性化状態２) .. controls +(1,0) and +(-2,0) .. (生成物);
\draw [<->,>=stealth'] ($(反応物)+(1.5,0)$) -- node [anchor=east] {$E_1$} +(0,-1);
\draw [<->,>=stealth'] (活性化状態１) -- node [anchor=east] {$E_2$} (活性化状態１ |- 下の線);
\draw [<->,>=stealth'] (反応中間体) -- node [above=10pt,anchor=east] {$E_3$} (反応中間体 |- 下の線);
\draw [<->,>=stealth'] (活性化状態２) -- node [above=10pt,anchor=east] {$E_4$} (活性化状態２ |- 下の線);
\node at ($(反応物)+(0,0.3)$) {反応物};
\node at ($(生成物)+(0,0.3)$) {生成物};
\node at ($(反応中間体)+(0,0.3)$) {\bf{M}};
\node at ($(反応中間体)+(0.2,0.8)$) {反応中間体};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
[hoge/.style={draw,fill=white,circle,inner sep=1pt}]
%\draw (0,0) node [hoge] {\gt{A5}} -- ++(0.8,0) node [hoge] {\gt{A4}} -- ++(0,0.8) node [hoge] {\gt{A3}} -- ++(0,0.8) node [hoge] {\gt{A2}} -- ++(0,0.8) node [hoge] {\gt{A1}} -- ++(0,0.8) node [hoge] {\gt{S2}};
%\foreach \x in {8,16,...,40}
%\draw (\x mm,8mm) -- ++($(8mm,8mm)+(\x mm,0)$) node [hoge] {\gt{A5}};
\coordinate (原点１) at (0,0);
\coordinate (原点２) at (4.8,0.8);
\coordinate (原点３) at (9.6,1.6);
\foreach \point in {原点１,原点２,原点３}
{\draw (\point) -- ++(0.8,0) -- ++(0,3.2) -- ++(1.6,0) -- ++(0,-0.8);
\draw ($(\point)+(0.8,0.8)$) -- +(0.8,0);
\draw ($(\point)+(0.8,3.2)$) -- +(-0.8,0);
\draw [densely dotted] ($(\point)+(0,3.2)$) -- +(-1,0);
\draw [densely dotted] ($(\point)+(2.4,2.4)$) -- +(0,-0.6);
\draw [densely dotted] ($(\point)+(2.4,3.2)$) -- +(1,0);
\draw [densely dotted] ($(\point)+(0.4,-0.4)$) rectangle ($(\point)+(1.2,2.8)$);}
\foreach \point in {原点１,原点２}
\draw ($(\point)+(1.6,0.8)$) -- +(3.2,0);
\foreach \point in {原点２,原点３}
\draw (\point) -- +(-0.8,0);
\draw [densely dotted] (原点１) -- +(-1,0);
\draw [densely dotted] ($(原点３)+(1.6,0.8)$) -- +(1,0);
%ここからnode
\foreach \point in {原点１,原点２,原点３}{
\node at (\point) [hoge] {\gt{A5}};
\node at ($(\point)+(2.4,2.4)$) [hoge] {\gt{A1}};
\foreach \a/\atext in {0/A4,8/A3,16/A2,24/A1}{
\node at ($(\point)+(0.8,\a mm)$) [hoge] {\gt{\atext}};
\foreach \b/\btext in {0/S1,8/S2,16/S1,24/S2}
\node at ($(\point)+(\b mm,3.2)$) [hoge] {\gt{\btext}};}}
\foreach \point in {原点１,原点２}{
\foreach \c/\ctext in {0,8,16,24}
\node at ($(\point)+(1.6,0.8)+(\c mm,0)$) [hoge] {\gt{A5}};
\node at ($(\point)+(3.2,0.3)$) {\mbox{\tate $\biggggggggg\}$}};
\node at ($(\point)+(3.2,-0.1)$) {ペンタペプチド};}
\node at ($(原点３)+(1.6,0.8)$) [hoge] {\gt{A5}};
\draw [draw=none] (原点２) -- ($(原点２)+(0.8,-2.5)$) node (テトラペプチド) [anchor=north] {テトラペプチド};
\draw [->,>=stealth'] (テトラペプチド) -- ($(原点１)+(1.2,-0.4)$);
\draw [->,>=stealth'] (テトラペプチド) -- ($(原点２)+(0.8,-0.4)$);
\draw [->,>=stealth'] (テトラペプチド) -- ($(原点３)+(0.8,-0.4)$);
\end{tikzpicture}

\br{1}

\begin{tabular}{L{3zw}cc}
\支柱*[6zw]{\ajKakkoHira{あ}} & {\nousece
\setatomsep{3em}
\setbondoffset{1.5pt}
\setcrambond{2pt}{}{}
\raisebox{-1zw}{$\Biggggggggl[$}\hspace{-3.5zw}\chemfig{-[:-30,0.7]O-[:30,0.7]?(-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]OH)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[2,0.45]H)(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})
    (-[:-30,0.7]O-[:30,0.7]?[b](-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]R|^1)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45,,]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[2,0.45]H)(-[:-30,0.7]O-[:30,0.7])(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})-[3,0.9]O-[4,1.2]?[b](-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}}))
    -[3,0.9]O-[4,1.2]?(-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}})}\hspace{-0.7zw}\raisebox{-1zw}{$\Biggggggggr]_n$}} & \chemfig{-[,0.9]R^1|{}}\text{： }\chemfig{-[,0.7]O-C(=[6]O)-CH(-[2]CH3)-OH} \\%改行
\支柱*[6zw]{\ajKakkoHira{い}} & {\nousece
\setatomsep{3em}
\setbondoffset{1.5pt}
\setcrambond{2pt}{}{}
\raisebox{-1zw}{$\Biggggggggl[$}\hspace{-3.5zw}\chemfig{-[:-30,0.7]O-[:30,0.7]?(-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]OH)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[6,0.45]H)(-[:-30,0.2,,,draw=none]{\small\ajMaru{1}})
    (-[:30,0.7]O-[:-30,0.7]?[b](-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]H)(-[6,0.45]CH_2OH(-[:170,0.27,,,draw=none]{\small\ajMaru{6}}))(-[:210,0.2,,,draw=none]{\small\ajMaru{5}})-[,1.2,,,line width=2.2pt]O>[1,0.9](-[2,0.45]H)(-[:-30,0.7]O-[:30,0.7])(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})-[3,0.9](-[6,0.45]H)(-[2,0.45]N(-[2,0.6]H)-[0,0.6]C(=[2,0.6]O)-[0,0.6]CH_3)(-[:30,0.2,,,draw=none]{\small\ajMaru{2}})-[4,1.2]?[b](-[2,0.45]H)(-[6,0.45]R|^2)(-[:170,0.2,,,draw=none]{\small\ajMaru{3}}))
    -[3,0.9]O-[4,1.2]?(-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}})}\hspace{-0.7zw}\raisebox{-1zw}{$\Biggggggggr]_n$}} & \chemfig{-[,0.9]R^2|{}}\text{： }\chemfig{-[,0.7]O-C(=[6]O)-CH(-[2]CH3)-OH} \\%改行
\支柱*[6zw]{\ajKakkoHira{う}} & {\nousece
\setatomsep{3em}
\setbondoffset{1.5pt}
\setcrambond{2pt}{}{}
\raisebox{-1zw}{$\Biggggggggl[$}\hspace{-3.5zw}\chemfig{-[:-30,0.7]O-[:30,0.7]?(-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]OH)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[2,0.45]H)(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})
    (-[:-30,0.7]O-[:30,0.7]?[b](-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]R|^3)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45,,]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[2,0.45]H)(-[:-30,0.7]O-[:30,0.7])(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})-[3,0.9]O-[4,1.2]?[b](-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}}))
    -[3,0.9]O-[4,1.2]?(-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}})}\hspace{-0.7zw}\raisebox{-1zw}{$\Biggggggggr]_n$}} & \chemfig{-[,0.9]R^3|{}}\text{： }\chemfig{-[,0.7]O-CH(-[2]CH3)-C(=[6]O)-OH} \\%改行
\支柱*[6zw]{\ajKakkoHira{え}} & {\nousece
\setatomsep{3em}
\setbondoffset{1.5pt}
\setcrambond{2pt}{}{}
\raisebox{-1zw}{$\Biggggggggl[$}\hspace{-3.5zw}\chemfig{-[:-30,0.7]O-[:30,0.7]?(-[2,0.45]H)(-[0,0.25,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]OH)(-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{3}})-[,1.2,,,line width=2.4pt](-[2,0.45]H)(-[6,0.45]N(-[6,0.6]H)-[0,0.6]C(=[6,0.6]O)-[0,0.6]CH_3)(-[:-20,0.2,,,draw=none]{\small\ajMaru{2}})>[1,0.9](-[6,0.45]H)(-[:-30,0.2,,,draw=none]{\small\ajMaru{1}})
    (-[:30,0.7]O-[:-30,0.7]?[b](-[6,0.45]H)(-[:210,0.2,,,draw=none]{\small\ajMaru{4}})<[7,0.9](-[2,0.45]H)(-[6,0.45]CH_2OH(-[:170,0.27,,,draw=none]{\small\ajMaru{6}}))(-[:210,0.2,,,draw=none]{\small\ajMaru{5}})-[,1.2,,,line width=2.2pt]O>[1,0.9](-[2,0.45]H)(-[:-30,0.7]O-[:30,0.7])(-[:30,0.2,,,draw=none]{\small\ajMaru{1}})-[3,0.9](-[6,0.45]H)(-[2,0.45]N(-[2,0.6]H)-[0,0.6]C(=[2,0.6]O)-[0,0.6]CH_3)(-[:30,0.2,,,draw=none]{\small\ajMaru{2}})-[4,1.2]?[b](-[2,0.45]H)(-[6,0.45]R|^4)(-[:170,0.2,,,draw=none]{\small\ajMaru{3}}))
    -[3,0.9]O-[4,1.2]?(-[2,0.45]CH_2OH(-[:150,0.3,,,draw=none]{\small\ajMaru{6}}))(-[6,0.45]H)(-[:170,0.2,,,draw=none]{\small\ajMaru{5}})}\hspace{-0.7zw}\raisebox{-1zw}{$\Biggggggggr]_n$}} & \chemfig{-[,0.9]R^4|{}}\text{： }\chemfig{-[,0.7]O-CH(-[2]CH3)-C(=[6]O)-OH} \\
\end{tabular}

\br{1}

\begin{tikzpicture}
\draw (0,0) -- node [below=15pt] {Dの百分率$\〔\%〕$} (5,0) -- (5,5) -- (0,5) -- node [left=20pt] {\rotatebox{90}{モル百分率$\〔\%〕$}} cycle;
\foreach \x/\xtext in {1/20,2/40,3/60,4/80}
\draw [dashed] (\x cm,5) -- (\x cm,0) node [below=3pt] {\xtext};
\foreach \xx/\xxtext in {0/0,5/100}
\node [below=3pt] at (\xx cm,0) {\xxtext};
\foreach \y/\ytext in {1/20,2/40,3/60,4/80}
\draw [dashed] (5,\y cm) -- (0,\y cm) node [left=3pt] {\ytext};
\foreach \yy/\yytext in {0/0,5/100}
\node [left=3pt] at (0,\yy cm) {\yytext};
\draw [very thick] (0,5) .. controls +(1.1,-2) and +(-3,0.6) .. (5,0) node [near start,xshift=0.7cm] {\ce{H2O}};
\node at (2.5,-1.5){図１};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\node (キチン) at (0,0) {キチン};
\draw [->,>=stealth'] (キチン) -- node [anchor=south] {\parbox{8zw}{\baselineskip=9pt グリコシド結合を加水分解}} (4,0) node [anchor=west] {単糖\bf{A}\hspace{0.5zw}＋\hspace{0.5zw}単糖\bf{B}};
\draw [->,>=stealth'] (キチン.south) -- ++(0,-1.5) -- node [anchor=south] {\parbox{7zw}{\baselineskip=10pt 濃アルカリ中で加熱して中和}} ++(3.5,0) node [draw,fill=white] (キトサン) [anchor=west] {キトサン\hspace{0.5zw}＋\hspace{0.5zw}酢酸};
\draw [->,>=stealth'] ($(キトサン.south)+(-0.7,0)$) -- ++(0,-1.5) -- node [anchor=south] {\parbox{7zw}{\baselineskip=10pt ヒドロキシ基をメチル化}} ++(3.5,0);
\draw [->,>=stealth'] ($(キトサン.south)+(3,-1.5)$) -- node [anchor=south] {\parbox{7zw}{\baselineskip=10pt グリコシド結合を加水分解}} ++(3.5,0) node [anchor=west] {単糖\bf{C}};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path coordinate (原点a) at (0,0)
coordinate (原点b) at (4.5,0)
coordinate (原点c) at (9,0)
coordinate (原点d) at (0,-4.5)
coordinate (原点e) at (4.5,-4.5)
coordinate (原点f) at (9,-4.5);
\foreach \point/\pointtext in {原点a/\ajKakkoalph{a},原点b/\ajKakkoalph{b},原点c/\ajKakkoalph{c},原点d/\ajKakkoalph{d},原点e/\ajKakkoalph{e},原点f/\ajKakkoalph{f}}
\foreach \x/\xtext in {0/0,1/100,2/200}
{\draw (\point) -- node [left=5pt] {\mbox{\tate 電気伝導率}} +(0,3) node [left=6pt] {\pointtext};
\draw (\point) -- node [below=15pt] {加えた酢酸水溶液の量$\〔\mL〕$} +(2,0);
\draw ($(\point)+(\x cm,5pt)$) -- +(0,-5pt) node [below=2pt] {\xtext};}
\draw [very thick] ($(原点a)+(0,2.5)$) -- ++(1,-2) -- ++(1,0.2);
\draw [very thick] ($(原点b)+(0,2.5)$) -- ++(1,-2) -- ++(1,0);
\draw [very thick] ($(原点c)+(0,2.5)$) -- ++(1,-2) -- ++(1,-0.2);
\draw [very thick] ($(原点d)+(0,1.5)$) -- ++(1,1.3) -- ++(1,0.2);
\draw [very thick] ($(原点e)+(0,1.5)$) -- ++(1,1.3) -- ++(1,0);
\draw [very thick] ($(原点f)+(0,1.5)$) -- ++(1,1.3) -- ++(1,-0.2);
\end{tikzpicture}

\br{1}

\begin{align*}
\chemname[-2zw]{\chemfig{3H-C~C-H}}{アセチレン}&　\ce{->[　　\mbox{触媒}　　]}　\chemname[-2zw]{\benzenefig{*6(=-=-=-)}}{ベンゼン}\frtext{\ajKakko{1}\hspace{5zw}} \\
\chemname[-2zw]{\chemfig{3H3C-C~C-CH3}}{化合物\bf{A}}&　\ce{->[　　\mbox{触媒}　　]}　\sikaku{あ}\frtext{\ajKakko{2}\hspace{5zw}} \\
\chemname[-2zw]{\chemfig{3H-C~C-CH3}}{化合物\bf{B}}&　\raisebox{-3zw}{\tikz\node {}child[grow=right]{child[->,>=stealth']{node[anchor=west]{\sikaku{う}}} child[->,>=stealth']{node[anchor=west]{\sikaku{い}}}edge from parent node[above]{\hspace{0.5zw}触媒\hspace{0.5zw}}};}\frtext{\ajKakko{3}\hspace{5zw}} \\
\sikaku{お}&　\ce{->[　　\mbox{触媒}　　]}　\chemname{\benzenefig{*6((-[:-150,1.2]H_3C)=(-[6,1.2,,2]H_2C-[:-10,1.7]CH_2-[:80,1.7,1]C?[a]H_2)-?[a]=(-[:15,1.2]CH_2-[:100,1.7,1,1]CH_2-[:190,1.7]H_2C?[b])-?[b]=(-[:150,1.2]H)-)}}{化合物\bf{C}}\frtext{\ajKakko{4}\hspace{5zw}}
\end{align*}

\br{1}

{\nousece
\setatomsep{3em}
\setbondoffset{2pt}
\setcrambond{2pt}{}{}
\chemname{\chemfig{%
H-[6,0.5]?(-[6,0.5,1,]O-[4,0.6]H_3C)<[:-60,0.8](-[2,0.5]OCH_3)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]OCH_3)>[:60,0.8](-[2,0.5]H)(-[6,0.5]OH)-[:120,0.8]O-[4,1.2]?(-[2,0.5]CH_2OCH_3)(-[6,0.5]H)}}{単糖\bf{G}}\hspace{2zw}\chemname{\chemfig{%
H_3C-[,0.6]O-[6,0.5,1,]?(-[6,0.5]H)<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]OH)>[:60,0.8](-[2,0.5]H)(-[6,0.5]OH)-[:120,0.8]O-[4,1.2]?(-[2,0.5]CH_2OCH_3)(-[6,0.5]H)}}{単糖\bf{H}}\hspace{2zw}\chemname{\chemfig{%
H_3C-[,0.6]O-[6,0.5,1,]?(-[6,0.5]H)<[:-60,0.8](-[2,0.5]H)(-[6,0.5]O-[4,0.6]H_3C)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]O-[0,0.6]CH_3)>[:60,0.8](-[2,0.5]H)(-[6,0.5]OH)-[:120,0.8]O-[4,1.2]?(-[2,0.5]H)(-[6,0.5]CH_3)}}{単糖\bf{I}}}

\br{1}

{\nousece
\setatomsep{3em}
\setbondoffset{1pt}
\setcrambond{2pt}{}{}
\chemname[-2zw]{\chemfig{HO-[2,0.5,2]?[a](-[2,0.5]H)<[:-60,0.8](-[2,0.5]OH(-[:240,1.5](-[:150,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-30,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])))(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](%ここから右へ
-[:55,1.7]O-[6,0.5](>[:120,0.8]?[b](-[2,0.5]H)(-[6,0.5,,2]HO))(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[2,0.5]O-[,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[b](-[2,0.5]CH_2OH)(-[6,0.5]H)%右ここまで
)(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[a](-[2,0.5]CH_2OH)(-[6,0.5]H)}}{\ajKakkoHira{か}}\hspace{2zw}\chemname[-2zw]{\chemfig{O(-[4,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))-[2,0.5]?[a](-[2,0.5]H)<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](%ここから右へ
-[:55,0.7]O-[:55,0.7]?[b](-[2,0.5]H)<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[2,0.5]O-[,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[b](-[2,0.5]CH_2OH)(-[6,0.5]H)%右ここまで
)(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[a](-[2,0.5]CH_2OH)(-[6,0.5]H)}}{\ajKakkoHira{き}}

\br{1}

\chemname[1zw]{\chemfig{H-[6,0.5]?[a](-[6,0.5,,2]HO)<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[2,0.5]H)(-[6,0.5]O-[,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))-[:120,0.8]O-[4,1.2]?[a](-[6,0.5]H)(%ここから左へ
-[2,0.5]CH_2-[:150,0.7]O-[:150,0.6]?[b](-[2,0.5]H)<[:-120,0.8](-[2,0.5]H)(-[6,0.5]NH_2)-[4,1.2,,,line width=2.4pt](-[2,0.5]OH)(-[6,0.5]H)>[:120,0.8](-[2,0.5]H)(-[6,0.5,,2]HO)-[:60,0.8](-[2,0.5]CH_2(-[:150,0.7]O-[:150,0.6](-[:60,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:240,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])))(-[6,0.5]H)-[,1.2]O?[b])}}{\ajKakkoHira{く}}\hspace{2zw}\chemname[1zw]{\chemfig{H-[6,0.5]?[a](-[6,0.5]O-[4,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[6,0.5]H)(%ここから右へ
-[:55,1.7]O-[6,0.5](>[:120,0.8]?[b](-[2,0.5]H)(-[6,0.5,,2]HO))(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[2,0.5]O-[,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[b](-[6,0.5]H)(-[2,0.5]CH_2%ここから左へ戻る
-[:150,0.7]O-[:150,0.6]?[c](-[2,0.5]H)<[:-120,0.8](-[2,0.5]H)(-[6,0.5]NH_2)-[4,1.2,,,line width=2.4pt](-[2,0.5]OH)(-[6,0.5]H)>[:120,0.8](-[2,0.5]H)(-[6,0.5,,2]HO)-[:60,0.8](-[2,0.5]CH_2OH)(-[6,0.5]H)-[,1.2]O?[c]%左おしまい
))-[:120,0.8]O-[4,1.2]?[a](-[2,0.5]CH_2OH)(-[6,0.5]H)}}{\ajKakkoHira{け}}

\br{1}

\chemname[1zw]{\chemfig{H-[6,0.5]?[a](-[6,0.5,,2]HO)<[:-60,0.8](-[2,0.5]OH)(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[6,0.5]H)(%ここから右へ
-[:55,1.7]O-[6,0.5](>[:120,0.8]?[b](-[2,0.5]H)(-[6,0.5,,2]HO))(-[6,0.5]H)-[,1.2,,,line width=2.4pt](-[2,0.5]H)(-[6,0.5]NH_2)>[:60,0.8](-[2,0.5]O-[,0.5](-[:90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:-90,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))(-[6,0.5]H)-[:120,0.8]O-[4,1.2]?[b](-[6,0.5]H)(-[2,0.5]CH_2%ここから左へ戻る
-[:150,0.7]O-[:150,0.6]?[c](-[2,0.5]H)<[:-120,0.8](-[2,0.5]H)(-[6,0.5]NH_2)-[4,1.2,,,line width=2.4pt](-[2,0.5]OH)(-[6,0.5]H)>[:120,0.8](-[2,0.5]H)(-[6,0.5,,2]HO)-[:60,0.8](-[2,0.5]CH_2-[:150,0.7]O-[:150,0.6](-[:60,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}])(-[:240,0.375,,,decorate,decoration={snake,amplitude=0.6mm,segment length=1.5mm,post length=0mm}]))(-[6,0.5]H)-[,1.2]O?[c]%左おしまい
))-[:120,0.8]O-[4,1.2]?[a](-[2,0.5]CH_2OH)(-[6,0.5]H)}}{\ajKakkoHira{こ}}}

\br{1}

\begin{tikzpicture}
[edge from parent fork right,grow=right,parent anchor=east,level distance=1.5cm,sibling distance=1.5cm,edge from parent/.style={draw,->,>=stealth'}]
\node {医学部志望？} child [sibling distance=5cm] {node [xshift=3cm] {２次対策に余裕ある？} child [sibling distance=2.5cm] {node [draw,rounded corners=4pt,xshift=5.5cm] {\parbox{20zw}{\baselineskip=10pt $6:4$くらいで２次を優先かな。センターの方は足を切られない程度に社会と国語はちゃんとやっておく感じ。化学については発展例題・受験科テスト，それと無機や有機の知識固めかな。}} edge from parent node [near end,above] {\footnotesize NO}} child [sibling distance=2.5cm] {node [draw,rounded corners=4pt,xshift=5.5cm] {\parbox{20zw}{\baselineskip=10pt $1:1$くらいの重みで良いんじゃないでしょうか。センターは社会・国語を優先的に，化学については実力演習や問題集をバンバンやると良いと思います。}} edge from parent node [near end,below] {\footnotesize YES}} edge from parent node [near end,above] {\footnotesize NO}} child [sibling distance=5cm] {node [xshift=3cm] {２次対策に余裕ある？} child [sibling distance=2.5cm] {node [draw,rounded corners=4pt,xshift=5.5cm] {\parbox{20zw}{\baselineskip=10pt ここは一番難しいけど，$6:4$〜$7:3$位の比率でセンター優先かなぁ。センターで事実上の足切り食らうと２次対策が意味なさないから。化学については前期の発展例題と受験科テスト中心ですね。}} edge from parent node [near end,above] {\footnotesize NO}} child  [sibling distance=2.5cm] {node [draw,rounded corners=4pt,xshift=5.5cm] {\parbox{20zw}{\baselineskip=10pt $7:3$でセンター重視で良いと思います。２次対策に余裕があるなら後期の出願も攻めたいのでセンターで830〜850点とかを狙いたいよね。化学については演習を受けながら，気になった分野の補強をしらみつぶし的にやっていけば良いでしょう。}} edge from parent node [near end,below] {\footnotesize YES}} edge from parent node [near end,below]{\footnotesize YES}};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path
coordinate (Z1) at (0,0)
coordinate (Z2) at ($(Z1)+(2.5,0)$)
coordinate (Z3) at ($(Z2)+(2.5,0)$)
coordinate (Z4) at ($(Z3)+(2.5,0)$)
coordinate (Z5) at ($(Z4)+(2.5,0)$)
coordinate (Z6) at ($(Z5)+(0.6,1.3)$)
coordinate (Z7) at ($(Z6)+(-2.5,0)$)
coordinate (Z8) at ($(Z7)+(-2.5,0)$)
coordinate (Z9) at ($(Z8)+(-2.5,0)$)
coordinate (Z10) at ($(Z9)+(-2.5,0)$)
coordinate (X1) at ($(Z2)!.5!(Z10)$)
coordinate (X2) at ($(Z3)!.5!(Z9)$)
coordinate (X3) at ($(Z4)!.5!(Z8)$)
coordinate (X4) at ($(Z5)!.5!(Z7)$)
coordinate (Y1) at ($(X1)+(0,1.5)$)
coordinate (Y8) at ($(X1)-(0,1.5)$)
coordinate (Y2) at ($(X2)+(0,1.5)$)
coordinate (Y7) at ($(X2)-(0,1.5)$)
coordinate (Y3) at ($(X3)+(0,1.5)$)
coordinate (Y6) at ($(X3)-(0,1.5)$)
coordinate (Y4) at ($(X4)+(0,1.5)$)
coordinate (Y5) at ($(X4)-(0,1.5)$);
\draw [thick] (Y1) -- (Y8);
\draw [thick] (Y2) -- (Y7);
\draw [thick] (Y3) -- (Y6);
\draw [thick] (Y4) -- (Y5);
\draw [thick] (Z1) -- (Z9) -- (Z3) -- (Z7) -- (Z5);
\draw [thick] (Z10) -- (Z2) -- (Z8) -- (Z4) -- (Z6);
\draw [dashed,thick] (Z10) -- (Y1) -- (Z9) -- (Y2) -- (Z8) -- (Y3) -- (Z7) -- (Y4) -- (Z6) -- (Y5) -- (Z7) -- (Y6) -- (Z8) -- (Y7) -- (Z9) -- (Y8) -- cycle;
\draw [dashed,thick] (Z1) -- (Z5) -- (Z6) -- (Z10) -- cycle;
\draw [dashed,thick] (Z1) -- (Y8) -- (Z2) -- (Y7) -- (Z3) -- (Y6) -- (Z4) -- (Y5) -- (Z5);
\draw [dashed,thick] (Z2) -- (Z9);
\draw [dashed,thick] (Z3) -- (Z8);
\draw [dashed,thick] (Z4) -- (Z7);
\draw [dashed,thick] (Y1) -- (Z2);
\draw [dashed,thick] (Y2) -- (Z3);
\draw [dashed,thick] (Y3) -- (Z4);
\draw [dashed,thick] (Y4) -- (Z5);
\foreach \point in {Z6,Z7,Z8,Z9,Z10}
\node [circle,draw,thick,fill=white,inner sep=0.5pt] at ($(\point)$) {{\LARGE Z}};
\draw [dashed,thick] (Y1) -- (Z1);
\draw [dashed,thick] (Y2) -- (Z2);
\draw [dashed,thick] (Y3) -- (Z3);
\draw [dashed,thick] (Y4) -- (Z4);
\foreach \point in {X1,X2,X3,X4}
\node [circle,draw,thick,fill=white,inner sep=0.5pt] at ($(\point)$) {{\LARGE X}};
\foreach \point in {Y1,Y2,Y3,Y4,Y5,Y6,Y7,Y8}
\node [circle,draw,thick,fill=white,inner sep=0.5pt] at ($(\point)$) {{\LARGE Y}};
\foreach \point in {Z1,Z2,Z3,Z4,Z5}
\node [circle,draw,thick,fill=white,inner sep=0.5pt] at ($(\point)$) {{\LARGE Z}};
\foreach \x in {0,10,20,30}
\fill (-\x pt,0.8) circle [radius=2.5pt];
\foreach \y in {0,10,20,30}
\fill ($(Z5)+(1,0)+(\y pt,0.8)$) circle [radius=2.5pt];
\end{tikzpicture}

\br{1}

\pgfdeclareradialshading{hoge}{\pgfpoint{-5bp}{5bp}}{%
color(0bp)=(black!0!white);
color(5bp)=(black!10!white);
color(7bp)=(black!70!white);
color(9bp)=(black!100!white)}
\begin{tikzpicture}
\path
coordinate (A) at (0,0)
coordinate (B) at ($(A)+(3.5,0)$)
coordinate (C) at ($(B)+(1.2,0.6)$)
coordinate (D) at ($(C)+(-3.5,0)$)
coordinate (E) at ($(A)+(0,-3.5)$)
coordinate (F) at ($(B)+(0,-3.5)$)
coordinate (G) at ($(C)+(0,-3.5)$)
coordinate (H) at ($(D)+(0,-3.5)$)
coordinate (上面) at ($(A)!.5!(C)$)
coordinate (手前面) at ($(A)!.5!(F)$)
coordinate (左面) at ($(A)!.5!(H)$)
coordinate (奥面) at ($(C)!.5!(H)$)
coordinate (右面) at ($(B)!.5!(G)$)
coordinate (下面) at ($(E)!.5!(G)$)
coordinate (上A) at ($(A)!.25!(G)$)
coordinate (上B) at ($(C)!.25!(E)$)
coordinate (下A) at ($(B)!.75!(H)$)
coordinate (下B) at ($(D)!.75!(F)$);
\path
[draw] (上A) -- (A)
[draw] (上A) -- (上面)
[draw] (上A) -- (手前面)
[draw] (上A) -- (左面);
\path
[draw] (上B) -- (C)
[draw] (上B) -- (上面)
[draw] (上B) -- (奥面)
[draw] (上B) -- (右面);
\path
[draw] (下A) -- (H)
[draw] (下A) -- (左面)
[draw] (下A) -- (奥面)
[draw] (下A) -- (下面);
\path
[draw] (下B) -- (F)
[draw] (下B) -- (手前面)
[draw] (下B) -- (右面)
[draw] (下B) -- (下面);
\foreach \point in {上B,下A}
\shade [shading=hoge] ($(\point)$) circle (0.35);
\draw (A) -- (B) -- (C) -- (D) -- cycle;
\draw (A) -- (E) -- (F) -- (B);
\draw (F) -- (G) -- (C);
\draw [dashed] (D) -- (H) -- (E);
\draw [dashed] (H) -- (G);
\draw [dashed] ($(A)!.5!(B)$) -- ($(C)!.5!(D)$) -- ($(G)!.5!(H)$) -- ($(E)!.5!(F)$) -- cycle;
\draw [dashed] ($(A)!.5!(E)$) -- ($(B)!.5!(F)$) -- ($(C)!.5!(G)$) -- ($(D)!.5!(H)$) -- cycle;
\draw [dashed] ($(A)!.5!(D)$) -- ($(B)!.5!(C)$) -- ($(F)!.5!(G)$) -- ($(E)!.5!(H)$) -- cycle;
\draw [dashed] (上面) -- (下面);
\draw [dashed] (左面) -- (右面);
\draw [dashed] (手前面) -- (奥面);
\foreach \point in {A,B,C,D,E,F,G,H,上面,手前面,左面,奥面,右面,下面,上A,下B}
\shade [shading=hoge] ($(\point)$) circle (0.35);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
[hoge/.style={draw=black,double,double=black!20!white,double distance=2.5pt}]
\path
coordinate (A) at (0,0)
coordinate (B) at ($(A)+(6,0)$)
coordinate (C) at ($(B)+(3.8,2.3)$)
coordinate (D) at ($(C)+(-5.6,0)$)
coordinate (E) at ($(A)+(0,-3.5)$)
coordinate (F) at ($(B)+(0,-3.5)$)
coordinate (G) at ($(C)+(0,-3.5)$)
coordinate (H) at ($(D)+(0,-3.5)$)
coordinate (手前面) at ($($(A)!.5!(E)$)!.5!(F)$)
coordinate (左面) at ($($(A)!.5!(E)$)!.5!(D)$)
coordinate (奥面) at ($($(C)!.5!(G)$)!.5!(H)$)
coordinate (右面) at ($($(B)!.5!(F)$)!.5!(C)$)
coordinate (重心) at ($(A)!.5!(G)$);
\draw [name path=EH,densely dashed] (E) -- (H) coordinate (EH);
\draw [name path=GH,densely dashed] (G) -- (H) coordinate (GH);
\draw [name path=FG] (F) -- (G) coordinate (FG);
\draw [name path=EF] (E) -- (F) coordinate (EF);
\draw (A) -- node [above=5pt] {$a$} (D) -- node [above=3pt] {$a$} (C) -- (B);
\draw (C) -- (G);
\draw [densely dashed] (D) -- (H);
%以下，内部の結合
\draw [hoge] (左面) -- (A);
\draw [hoge] (左面) -- (D);
\draw [hoge] (左面) -- (重心);
\draw [hoge] (奥面) -- (H);
\draw [hoge] (奥面) -- (G);
\draw [hoge] (奥面) -- (重心);
\draw [hoge] (右面) -- (重心);
\draw [hoge] (右面) -- (B);
\draw [hoge] (右面) -- (C);
\filldraw [fill=black] (H) circle [radius=7pt];
\draw [hoge] (手前面) -- (重心);
\draw [hoge] (手前面) -- (E);
\draw [hoge] (手前面) -- (F);
\draw (E) -- node [left=3pt] {$c$} (A) -- (B) -- (F);
%以下，垂線たち
\draw [densely dashed] (手前面) -- node [anchor=west,yshift=-2pt] {{\small$\bun14c$}} (手前面|-EF);
\path [name path=左面から下] (左面) -- +(0,-5);
\draw [name intersections={of=左面から下 and EH, by=t1}] [densely dashed] (左面) -- node [anchor=east,yshift=-2pt] {$\bun34c$} (t1);
\draw [densely dashed] (奥面) -- node [anchor=east,yshift=-3pt] {{\small$\bun14c$}} (奥面|-GH);
\path [name path=右面から下] (右面) -- +(0,-5);
\draw [name intersections={of=右面から下 and FG, by=t2}] [densely dashed] (右面) -- node [anchor=east,yshift=-0.8cm] {$\bun34c$} (t2);
\draw [densely dashed] (重心) -- node [anchor=west,yshift=-7pt] {{\small}$\bun12c$} ($(E)!.5!(G)$);
\foreach \point in {A,B,C,D,E,F,G}
\filldraw [fill=black] (\point) circle [radius=7pt];
\foreach \point in {左面,奥面,右面,手前面}
\filldraw [fill=white] (\point) circle [radius=7pt];
\filldraw [fill=black!60!white] (重心) circle [radius=7pt];
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
[hoge/.style={draw=black,double,double=black!20!white,double distance=2.5pt}]
\path
coordinate (E) at (0,0)
coordinate (F) at ($(E)+(6,0)$)
coordinate (B) at ($(F) +(0,3.5)$)
coordinate (A) at ($(E)+(0,3.5)$)
coordinate (内部) at ($($(A)!.5!(E)$)!.5!(F)$);
\draw (E) -- (F) -- node [anchor=west] {{\small$c$}} (B) -- node [anchor=south] {{\small$a$}} (A) -- node [anchor=east] {{\small$c$}} cycle;
\draw [hoge] (E) -- (内部) -- (F);
\draw [densely dashed] ($(A)!.5!(B)$) -- node [anchor=west,yshift=2pt] {{\small$\bun34c$}} (内部);
\draw [densely dashed] ($(E)!.5!(F)$) -- node [anchor=west,yshift=-2pt] {{\small$\bun14c$}} (内部);
\node at ($($(E)!.75!(F)$)+(0,-12pt)$) {{\small$\bun12a$}};
\node at ($($(E)!.25!(F)$)+(0,-12pt)$) {{\small$\bun12a$}};
\foreach \point in {A,B,E,F}
\filldraw [fill=black] (\point) circle [radius=7pt];
\filldraw [fill=white] (内部) circle [radius=7pt];
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path coordinate (原点1) at (0,0)
coordinate (原点2) at (5,0)
coordinate (原点3) at (10,0)
coordinate (原点4) at (0,-3)
coordinate (原点5) at (5,-3)
coordinate (原点6) at (10,-3);
\foreach \point/\pointtext in {原点1/\ajKakko{1},原点2/\ajKakko{2},原点3/\ajKakko{3},原点4/\ajKakko{4},原点5/\ajKakko{5},原点6/\ajKakko{6}}
{\draw [->,>=stealth'] (\point) --  +(0,2) node [above left=8pt,yshift=-8pt] {\pointtext} node [right=3pt] {$Z$};
\draw [->,>=stealth'] (\point) -- +(3.5,0) node [above right=0pt] {$\bun{n}{V}$};
\draw [dashed] ($(\point)+(0,1)$) node [anchor=east,xshift=-3pt] {1} -- +(3.5,0);}
\draw [very thick] ($(原点1)+(0,1)$) .. controls +(0.8,-1.5) and +(-1,-1) .. ($(原点1)+(3.3,1.8)$);
\draw [very thick] ($(原点2)+(0,1)$) -- +(3.5,0.5);
\draw [very thick] ($(原点3)+(0,1)$) .. controls +(0.8,1.5) and +(-1,1) .. ($(原点3)+(3.3,0.2)$);
\draw [very thick] ($(原点4)+(0,1)$) -- +(3.5,-0.5);
\draw [very thick] ($(原点5)+(0,1)$) .. controls +(0.2,0.05) and +(-0.15,-0.15) .. ($(原点5)+(0.6,1.4)$) .. controls +(0.15,0.15) and +(-0.3,0) .. ($(原点5)+(1.2,1.8)$) .. controls +(0.35,0) and +(-0.1,0.01) .. ($(原点5)+(2.2,1.4)$) .. controls +(0.1,-0.05) and +(-0.25,0) .. ($(原点5)+(3.3,1.2)$);
\draw [very thick] ($(原点6)+(0,1)$) .. controls +(0.2,-0.05) and +(-0.15,+0.15) .. ($(原点6)+(0.6,0.5)$) .. controls +(0.15,-0.15) and +(-0.3,0) .. ($(原点6)+(1.2,0.1)$) .. controls +(0.35,0) and +(-0.1,-0.01) .. ($(原点6)+(2.2,0.5)$) .. controls +(0.1,0.05) and +(-0.25,0) .. ($(原点6)+(3.3,0.9)$);
\end{tikzpicture}

\br{1}

%\ajKakko{1}\hspace{13zw}\ajKakko{2}\hspace{13zw}\ajKakko{3}

\hspace{2zw}\makebox[14zw][l]{$\Bigggl[$\hspace{-1.2zw}\chemfig{-[,1.2]C(-[2]H)(-[6]H)-C(-[2]H)(-[6]Cl)-[,1.2]}\hspace{-1.2zw}$\Bigggr]_n$}\makebox[14zw][l]{$\Bigggl[$\hspace{-1.2zw}\chemfig{-[,1.2]C(-[2]H)(-[6]H)-C(-[2]H)(-[6]OH)-[,1.4]}\hspace{-1zw}$\Bigggr]_n$}\raisebox{2zw}{\scalebox{0.8}{\benzenefig{-[,1.2,,,dotted]{}-[:30,1.4]CH_2-[:-30,1.6]*6(-=(-[6,1.1]CH_2-[6,1.1]*6(=(-[:150,1.4]HO)-(-[:-150,1.6]CH_2-[:150,1.4]-[4,1.2,,,dotted])=-(-[:-30,1.4]H)=-))-=(-[:33,1.4]CH_2-[:-30,1.4]*6(-=(-[6,1.1]CH_2-[6,1.1]*6(=-(-[:-150,1.4]H)=(-[6,1.2]OH)-(-[:-30,1.4]CH_2-[:30,1.6]-[0,1.2,,,dotted])=-))-=(-[:30,1.4]CH_2-[:-30,1.6]{}-[0,1.2,,,dotted])-(-[2,1.2]OH)=))-(-[2,1.2]OH)=)}}}

%\ajKakko{4}\hspace{13zw}\ajKakko{5}\hspace{13zw}\ajKakko{6}

\hspace{2zw}\makebox[14zw][l]{\raisebox{-1zw}{$\Biggggl[$}\hspace{-1.2zw}\benzenefig{-[,2]C(-[2,1.4]H)(-[6,1.4]H)-[,1.6]C(-[2,1.4]H)(-[6,1.2]*6(=-=-=-))-[,2.5]}\hspace{-1.2zw}\raisebox{-1zw}{$\Biggggr]_n$}}\makebox[14zw][l]{$\Bigggl[$\hspace{-1.2zw}\chemfig{-[,1.2]C(-[2]H)(-[6]H)-C(-[2]H)(-[6]OCOCH3)-[,3.3]}\hspace{-1.2zw}$\Bigggr]_n$}\raisebox{-1zw}{$\Bigggl[$}\hspace{-1.2zw}\chemfig{CH3| -[7]C(-[5]CH2| -[4,1.2])=C(-[1]{}H)-[7]{}CH2-[,1.2]}\hspace{-1.2zw}\raisebox{-1zw}{$\Bigggr]_n$}

\br{0.5}

\noindent \hfil 図３−１　様々な合成ポリマーの例

\br{1}

\noindent \hfil{\setcrambond{4pt}{}{1pt}\setbondoffset{3pt}\setlength{\fboxsep}{0.75pt}%
\chemfig{-[:-20,1.7]C(<:[:-120,1.6]H)(<[:-60,1.6]H)-[:20,1.7]C(<:[:120,1.6]H)(<[:60,1.6]CH3)-[:-20,1.7]C(<:[:-120,1.6]H)(<[:-60,1.6]H)-[:20,1.7]C(<:[:120,1.6]\fbox{\makebox[0.8zw][c]{\gt{B}}})(<[:60,1.6]\fbox{\makebox[0.8zw][c]{\gt{A}}})-[:-20,1.7]C(<:[:-120,1.6]H)(<[:-60,1.6]H)-[:20,1.7]C(<:[:120,1.6]\fbox{\makebox[0.8zw][c]{\gt{D}}})(<[:60,1.6]\fbox{\makebox[0.8zw][c]{\gt{C}}})-[:-20,1.7]C(<:[:-120,1.6]H)(<[:-60,1.6]H)-[:20,1.7]C(<:[:120,1.6]\fbox{\makebox[0.8zw][c]{\gt{F}}})(<[:60,1.6]\fbox{\makebox[0.8zw][c]{\gt{E}}})-[:-20,1.7]}}

\br{0.5}

\noindent \hfil 図３−２　アイソタクチックポリプロピレン

\br{1}

\noindent \hfil{\setcrambond{4pt}{}{1pt}\setbondoffset{3pt}\setlength{\fboxsep}{0.75pt}%
\benzenefig{-[:-20,2.4]C(<:[:-120,2.2]H)(<[:-60,2.2]H)-[:20,2.4]C(<:[:120,1.5]{}-[:120,0.2,,,draw=none]*6(=-=-=-))(<[:60,2.2]H)-[:-20,2.4]C(<:[:-120,2.2]H)(<[:-60,2.2]H)-[:20,2.4]C(<:[:120,2.2]\fbox{\makebox[0.8zw][c]{\gt{H}}})(<[:60,2.2]\fbox{\makebox[0.8zw][c]{\gt{G}}})-[:-20,2.4]C(<:[:-120,2.2]H)(<[:-60,2.2]H)-[:20,2.4]C(<:[:120,2.2]\fbox{\makebox[0.8zw][c]{\gt{J}}})(<[:60,2.2]\fbox{\makebox[0.8zw][c]{\gt{I}}})-[:-20,2.4]C(<:[:-120,2.2]H)(<[:-60,2.2]H)-[:20,2.4]C(<:[:120,2.2]\fbox{\makebox[0.8zw][c]{\gt{L}}})(<[:60,2.2]\fbox{\makebox[0.8zw][c]{\gt{K}}})-[:-20,2.4]}}

\br{0.5}

\noindent \hfil 図３−３　シンジオタクチックポリスチレン

\br{1}

\noindent \hfil \benzenefig{C(-[3,1.6]H)(-[5,1.6]H)=[,1.4]C(-[1,1.6]CH_3)-[7,1.6]C(=[6,1.4]O)-[0,1.4]O-[,1.4]C(-[2,1.2]*6(-=-=-=))(-[6,1.2]*6(=-=-=-))-[0,1.2]*6(-=-=-=)}

\br{0.5}

\noindent \hfil 図３−４　メタクリル酸トリフェニルメチル

\br{1}

\begin{tikzpicture}
\draw [very thick] (0,0) -- node [above=-1.2cm] {$\pH$} ++(6*22mm,0) -- ++(0,2*60mm) -- ++(-6*22mm,0) node [above=0.25cm,xshift=0.5cm] {$\times 10^{-6}\,\molL$} -- node [left=1cm] {\rotatebox{90}{濃度}} cycle;
\foreach \x in {1,2,...,21}
\draw (6*\x mm,0) -- +(0,2*60mm);
\foreach \y in {1,2,...,28,30,31,...,59}
\draw (0,2*\y mm) -- +(6*22mm,0);
\draw [very thick,dash pattern=on 3pt off 3pt on 11pt off 4pt] (0,2*29mm) -- +(6*22mm,0);
\foreach \xx/\xxtext in {0/4.5,5/5.0,10/5.5,15/6.0,20/6.5}
\node at (6*\xx mm,-4mm) {\xxtext};
\foreach \yy/\yytext in {10/2,20/4,30/6,40/8,50/10}
\draw (0,2*\yy mm) -- +(-1.5mm,0) node [anchor=east] {\yytext};
\path
node [anchor=east] at (-1.5mm,0) {0}
node [anchor=east] at (-1.5mm,2*60mm) {12};
\draw [very thick] (0,2pt) .. controls +(2,0.2) and +(-2.4,-1.6) .. (6*13mm,2*8mm) .. controls +(2.4,1.6) and +(-0.5,-4) .. (131mm,120mm);
\draw [very thick,dotted] (25mm,120mm) .. controls +(0.5,-3) and +(-2.4,1.6) .. (6*13mm,2*8mm) .. controls +(2.4,-1.6) and +(-2,0.2) .. (132mm,2mm);
\end{tikzpicture}

図１　雨水の$\pH$と雨水中の炭酸の電離（$25\DegC$）

\begin{jquotation}(8zw)(8zw)[0pt]
{\small%
\noindent 現在の大気中の\ce{CO2}の分圧として$3.6\times10\,\Pa$を採用してある。

\noindent 横軸には$\pH$，縦軸には濃度（$\times 10^{-6}\,\molL$）が目盛ってあり，一点鎖線（\raisebox{0.3zw}{\tikz\draw[very thick,dash pattern=on 3pt off 3pt on 11pt off 4pt](0,0)--(1.5,0);}）は$[\ce{H2CO3}]$，実線（\raisebox{0.3zw}{\tikz\draw[very thick](0,0)--(1.5,0);}）は$[\ce{HCO3-}]$，破線（\raisebox{0.3zw}{\tikz\draw[very thick,dotted](0,0)--(1.5,0);}）は$[\ce{H+}]-[\ce{OH-}]$を表している。$[\ce{CO3^2-}]$の値は非常に小さいため，この図では横軸と重なってしまっている。}
\end{jquotation}

\br{1}

\begin{tikzpicture}
[hogearc/.style={x radius=0.5,y radius=0.15}]
\path
coordinate (原点左) at (0,0)
coordinate (原点右) at (5.5,0)
coordinate (左の左) at ($(原点左)+(-2,1)$)
coordinate (右の左) at ($(原点右)+(-2,1)$)
coordinate (右の右) at ($(原点右)+(4,1.3)$);
\node at ($(原点左)+(-3,3.5)$) {\ajKakkoroman{1}};
\node at ($(原点右)+(-3,3.5)$) {\ajKakkoroman{2}};
%まずは容器
\draw [very thick] (原点左) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{甲}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点左)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点左)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点左)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここからビーカー
\draw [very thick,fill=white] (左の左) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (左の左) arc [start angle=360,end angle =180,hogearc];
\draw ($(左の左)+(-0.5,-0.9)$) -- +(-0.2,-0.7) node [inner sep=1pt,anchor=north] {試料水溶液};
\draw [->,>=stealth']($(左の左)+(-0.5,-1.5pt)$) -- ($(原点左)+(-1.5,2.2)$) -- ($(原点左)+(0.7,2.2)$);
%ここまで左
%まずは容器
\draw [very thick] (原点右) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{甲}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点右)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点右)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点右)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここから左のビーカー
\path
coordinate (右の左１) at (右の左)
coordinate (右の左２) at ($(右の左１)+(0.75,0.3)$)
coordinate (右の左３) at ($(右の左２)+(0.75,0.3)$);
\foreach \point in {右の左３,右の左２,右の左１}
{\draw [very thick,fill=white] (\point) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (\point) arc [start angle=360,end angle =180,hogearc];}
\draw ($(右の左１)+(-0.5,-0.9)$) -- +(-0.2,-0.7) node [inner sep=1pt,anchor=north] {純水};
\draw ($(右の左２)+(-0.5,-0.9)$) -- +(0.1,-0.7) node [inner sep=1pt,anchor=north] {純水};
\draw ($(右の左３)+(-0.5,-0.9)$) -- +(0.1,-0.7) node [inner sep=1pt,anchor=north] {純水};
\draw [->,>=stealth']($(右の左１)+(-0.5,-1.5pt)$) -- ($(原点右)+(-1.3,2.2)$) -- ($(原点右)+(0.7,2.2)$);
%ここから右のビーカー
\path
coordinate (右の右１) at (右の右)
coordinate (右の右２) at ($(右の右１)+(0.75,0.3)$)
coordinate (右の右３) at ($(右の右２)+(0.75,0.3)$);
\foreach \point in {右の右３,右の右２,右の右１}
{\draw [very thick,fill=white] (\point) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (\point) arc [start angle=360,end angle =180,hogearc];}
\node at ($(右の右１)+(-0.5,-1.6)$) {容器１};
\node at ($(右の右２)+(-0.1,-1.6)$) {容器２};
\node at ($(右の右３)+(-0.5,0.5)$) {容器３};
\draw [->,>=stealth'] ($(原点右)+(1.2,2.2)$) -- ++(1.8,0) -- ($(右の右１)+(-0.5,-1pt)$);
\end{tikzpicture}

図１

\br{1}

\begin{tikzpicture}
[hogearc/.style={x radius=0.5,y radius=0.15}]
\path
coordinate (原点左上) at (0,0)
coordinate (原点右上) at ($(原点左上)+(2.5,0)$)
coordinate (原点左下) at ($(原点左上)+(0,-4.2)$)
coordinate (原点右下) at ($(原点左下)+(2.5,0)$)
coordinate (左上の左) at ($(原点左上)+(-1.45,1.4)$)
coordinate (右上の右) at ($(原点右上)+(4,1.4)$)
coordinate (左下の左) at ($(原点左下)+(-2,1)$)
coordinate (右下の右) at ($(原点右下)+(4,1.4)$);
\node at ($(原点左上)+(-3.5,3.2)$) {\ajKakkoroman{1}};
\node at ($(原点左下)+(-3.5,3.2)$) {\ajKakkoroman{2}};
%ここから左上
%まずは容器
\draw [very thick] (原点左上) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{乙}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点左上)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点左上)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点左上)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここからビーカー
\draw [very thick,fill=white] (左上の左) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (左上の左) arc [start angle=360,end angle =180,hogearc];
\draw ($(左上の左)+(-0.5,-0.9)$) -- +(-0.2,-0.7) node [inner sep=1pt,anchor=north] {試料水溶液};
\draw [->,>=stealth']($(左上の左)+(-0.5,-1.5pt)$) -- ($(原点左上)+(-1,2.2)$) -- ($(原点左上)+(0.7,2.2)$);
%ここから右上
%まずは容器
\draw [very thick] (原点右上) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{丙}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点右上)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点右上)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点右上)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここからビーカー
\draw [very thick,fill=white] (右上の右) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (右上の右) arc [start angle=360,end angle =180,hogearc];
\draw ($(右上の右)+(-0.5,-0.9)$) -- +(-0.2,-0.7) node [inner sep=1pt,anchor=north] {純水};
\draw [->,>=stealth'] ($(右上の右)+(-0.5,-1.5pt)$) -- ($(原点右上)+(2.5,2.2)$) -- ++(-1.5,0);
%ここから左下
%まずは容器
\draw [very thick] (原点左下) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{乙}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点左下)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点左下)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点左下)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここからビーカー
\path
coordinate (左下の左１) at (左下の左)
coordinate (左下の左２) at ($(左下の左１)+(0.55,0.4)$)
coordinate (左下の左３) at ($(左下の左２)+(0.55,0.4)$)
coordinate (左下の左４) at ($(左下の左３)+(0.55,0.4)$);
\foreach \point in {左下の左４,左下の左３,左下の左２,左下の左１}
{\draw [very thick,fill=white] (\point) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (\point) arc [start angle=360,end angle =180,hogearc];}
\draw ($(左下の左１)+(-0.5,-0.9)$) -- +(-0.2,-0.7) node [inner sep=1pt,anchor=north] {純水};
\draw ($(左下の左２)+(-0.3,-0.9)$) -- +(0.2,-0.5) node [inner sep=1pt,anchor=north] {純水};
\draw ($(左下の左３)+(-0.25,-0.9)$) -- +(0.15,-0.5) node [inner sep=1pt,anchor=north] {純水};
\draw ($(左下の左４)+(-0.2,-0.9)$) -- +(0.1,-0.5) node [inner sep=1pt,anchor=north] {純水};
\draw [->,>=stealth'] ($(左下の左１)+(-0.5,-1.5pt)$) -- ($(原点左下)+(-1.5,2.2)$) -- ($(原点左下)+(0.7,2.2)$);
\draw [->,>=stealth'] ($(原点左下)+(1.3,2.2)$) -- ($(原点右下)+(0.7,2.2)$);
%ここから右下
%まずは容器
\draw [very thick] (原点右下) -- ++(9*6pt+1pt,0) -- ++(0,3) -- node [anchor=south] {容器\gb{丙}} ++(-9*6pt-1pt,0) node [below right=5pt] {液体} -- cycle;
\foreach \x in {1,2,...,9}
\foreach \y in {1,2,...,8}
\foreach \z in {0,1,2,3}
\foreach \w in {0,1,2}
{\draw [very thin] ($(原点右下)+(0.5pt,0.5pt)+(-3pt,3pt)+(6*\x pt,2*1.73*3*\z pt)$) circle [radius=3pt];
\draw [very thin] ($(原点右下)+(0.5pt,0.5pt)+(0,1.73*3pt)+(0,3pt)+(6*\y pt,2*1.73*3*\w pt)$) circle [radius=3pt];}
\draw ($(原点右下)+(18pt,18pt)$) -- +(-6pt,-22pt) node [inner sep=1pt,anchor=north] {固体S};
%ここからビーカー
\path
coordinate (右下の右１) at (右下の右)
coordinate (右下の右２) at ($(右下の右１)+(0.5,0.4)$)
coordinate (右下の右３) at ($(右下の右２)+(0.5,0.4)$)
coordinate (右下の右４) at ($(右下の右３)+(0.5,0.4)$);
\foreach \point in {右下の右４,右下の右３,右下の右２,右下の右１}
{\draw [very thick,fill=white] (\point) arc [start angle=0,end angle =180,hogearc] -- +(0,-1.2) arc [start angle=180,end angle =360,hogearc] -- cycle;
\draw (\point) arc [start angle=360,end angle =180,hogearc];}
\node at ($(右下の右１)+(-0.5,-1.6)$) {容器R0};
\node at ($(右下の右２)+(0.25,-1.6)$) {容器R1};
\node at ($(右下の右３)+(-1.25,0.5)$) {容器R2};
\node at ($(右下の右４)+(-0.5,0.5)$) {容器R3};
\draw [->,>=stealth'] ($(原点右下)+(1.2,2.2)$) -- ++(1.7,0) -- ($(右下の右１)+(-0.5,-1.5pt)$);
\end{tikzpicture}

図２

\br{1}

\begin{tikzpicture}
%\tikzset{paint/.style={draw=#1,fill=#1},decorate with/.style={decorate,decoration={shape backgrounds,shape=#1,shape size=2.5mm}}}
[plot/.style={draw=black,fill=black,decorate,decoration={shape backgrounds,shape=diamond,shape size=2.25mm}}]
\draw (0,0) -- node [below=0.75] {時間（分）} ++(10,0) -- ++(0,6) -- ++(-10,0) -- node [left=5pt] {\rotatebox{90}{濃度}} cycle;
\foreach \x/\xtext in {2.5/10,5/20,7.5/30}
\draw (\x,3pt) -- (\x,0) node [below=5pt] {\xtext};
\node at (0,-5pt) [anchor=north] {0};
\node at (10,-5pt) [anchor=north] {40};
\foreach \y in {1,2,...,5}
\draw (0,\y) -- +(3pt,0);
%以下，プロット
\draw [plot] (0.25,1mm);
\draw [plot] (0.5,3mm);
\draw [plot] (0.75,7mm);
\draw [plot] (1,12mm);
\draw [plot] (1.25,16mm) node [above right=0.2] {C};
\draw [plot] (1.5,12mm);
\draw [plot] (1.75,7mm);
\draw [plot] (2,3mm);
\draw [plot] (2.25,2mm);
\draw [plot] (2.5,4mm);%10分
\draw [plot] (2.75,11mm);
\draw [plot] (3,20mm);
\draw [plot] (3.25,32mm);
\draw [plot] (3.5,45mm);
\draw [plot] (3.75,50mm) node [above right=0.2] {D};
\draw [plot] (4,45mm);
\draw [plot] (4.25,32mm);
\draw [plot] (4.5,20mm);
\draw [plot] (4.75,11mm);
\draw [plot] (5,4mm);%20分
\draw [plot] (5.25,2mm);
\draw [plot] (5.5,1mm);
\draw [plot] (5.75,2mm);
\draw [plot] (6,3mm);
\draw [plot] (6.25,6mm);
\draw [plot] (6.5,12mm);
\draw [plot] (6.75,19mm);
\draw [plot] (7,26mm);
\draw [plot] (7.25,31mm);
\draw [plot] (7.5,33mm) node [above right=0.2] {E};%30分
\draw [plot] (7.75,31mm);
\draw [plot] (8,26mm);
\draw [plot] (8.25,19mm);
\draw [plot] (8.5,12mm);
\draw [plot] (8.75,6mm);
\draw [plot] (9,3mm);
\draw [plot] (9.25,2mm);
\draw [plot] (9.5,1mm);
\draw [plot] (9.75,0.5mm);
\draw [plot] (10,0);
\end{tikzpicture}

図３

\br{1}

\begin{tikzpicture}
\path
coordinate (温水左) at (0,0)
coordinate (温水右) at ($(温水左)+(4.5,0)$);
%\draw [rounded corners=4pt] (-5pt,5pt) arc [start angle=90,end angle=0,radius=5pt] -- ++(0,-2) -- ++(4.5,0);
\filldraw [fill=black!30!white,draw=black] (0,-0.3) -- ++($(0,-1.7)+(0,5pt)$) arc [radius=5pt,start angle=180,end angle=270] -- ++($(4.5,0)+(-10pt,0)$) arc [radius=5pt,start angle=270,end angle=360] -- ++($(0,1.7)+(0,-5pt)$) -- cycle;
\draw [rounded corners=5pt] (-5pt,2pt) -- (0,0) -- ++(0,-2) -- ++(4.5,0) -- ++(0,2) -- ++(5pt,2pt);
\path
coordinate (ビーカー左) at ($(温水左)!.5!(温水右)+(-1,0.5)$)
coordinate (ビーカー右) at ($(温水左)!.5!(温水右)+(1,0.5)$);
\filldraw [fill=white,draw=black,rounded corners=5pt] ($(ビーカー左)+(-5pt,2pt)$) -- (ビーカー左) -- ++(0,-2.4) -- ++(2,0) -- (ビーカー右) -- ++(5pt,2pt);
\path
coordinate (フラスコ左) at ($(温水左)!.5!(温水右)+(-0.3,4.525)$)
coordinate (フラスコ右) at ($(温水左)!.5!(温水右)+(0.3,4.525)$)
coordinate (フラスコ液面左) at ($(温水左)!.5!(温水右)+(-0.3,4.525)+(-1.2,-2.975)$);
\filldraw [fill=black!30!white,draw=black] (フラスコ液面左) arc [radius=1.5,start angle=180,end angle=360] -- cycle;
\draw [rounded corners=3pt] ($(フラスコ左)+(-3pt,1.5pt)$) -- (フラスコ左) -- ++(0,-1.5) arc [radius=1.5,start angle=101.5,end angle=438.5] -- (フラスコ右) -- ++(3pt,1.5pt);
\begin{scope}[scale=0.75]
\path
coordinate (１) at (1.2,2)
coordinate (２) at (1.4,1.7)
coordinate (３) at (1.7,1.8)
coordinate (４) at (1.8,2.0)
coordinate (５) at (2.1,2.1)
coordinate (６) at (2.4,1.9)
coordinate (７) at (2.6,2.3)
coordinate (８) at (3.0,2.2)
coordinate (９) at (3.3,2.3)
coordinate (10) at (3.5,1.9)
coordinate (11) at (3.9,2.1)
coordinate (12) at (4.2,1.8);
\foreach \point in {１,２,３,４,５,６,７,８,９,10,11,12}
{\filldraw [fill=white,draw=black] (\point) -- ++(6pt,-2pt) -- ++(4pt,4pt) -- ++(-6pt,2pt) -- cycle;
\filldraw [fill=white,draw=black] ($(\point)+(6pt,-2pt)$) -- ++(0,-7pt) -- ++(4pt,4pt) -- ++(0,7pt) -- cycle;
\draw (\point) -- ++(0,-7pt) -- ++(6pt,-2pt);
\draw ($(\point)+(4pt,4pt)$) -- ++(0,-7pt) -- ++(6pt,-2pt);
\draw ($(\point)+(0,-7pt)$) -- ++(4pt,4pt);}
\end{scope}
\foreach \x in {1,12,2,11,3,10,4,9,5,8,6,7}
\filldraw [fill=black!30!white,draw=black] ($(1.6,-1.82)+(\x mm,0)$) circle [radius=2pt];
\foreach \x in {1,10,2,9,3,8,4,7,5,6}
\filldraw [fill=black!30!white,draw=black] ($(1.7,-1.74)+(\x mm,0)$) circle [radius=2pt];
\foreach \x in {1,7,2,6,3,5,4}
\filldraw [fill=black!30!white,draw=black] ($(1.9,-1.66)+(\x mm,0)$) circle [radius=2pt];
\foreach \x in {1,2.5}
\filldraw [fill=black!30!white,draw=black] ($(2.09,-1.5)+(\x mm,0)$) circle [radius=2pt];
\foreach \x in {1,4,3,2}
\filldraw [fill=black!30!white,draw=black] ($(2.0,-1.58)+(\x mm,0)$) circle [radius=2pt];
\node at (0.6,-1.4) {\parbox{3zw}{\baselineskip=3pt\centering {\small 温水\\（$90\DegC$）}}};
\node at ($(温水左)!.5!(温水右)+(0,-0.8)$) {{\small ヨウ素（固体）}};
\node at ($(温水左)!.5!(温水右)+(0,0.5)$) {{\small 氷水}};
\end{tikzpicture}

図２−１　ビーカーを温水（$90\DegC$）につけた直後の様子

\br{1}

{\setlength{\fboxsep}{0.9zw}\fbox{\makebox[12.5zw][c]{{\nousece\setatomsep{10pt}\setbondoffset{0pt}\chemname[-1zw]{\chemfig{*6((=[:210,1.2]O)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30]-[:-30]-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])---)}}{\hspace{4.5zw}化合物\gt{M}}}}}} \raisebox{-1zw}{→\gt{N}→\gt{O}→\gt{P}→\gt{Q}→\gt{R}→} {\setlength{\fboxsep}{0.6zw}\fbox{\makebox[13zw][c]{{\nousece\setatomsep{10pt}\setbondoffset{2pt}\chemname[-1zw]{\chemfig{*6((<:[:210,1.4]HO)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30](<[2,1.2]OH)-[:-30](<[6,1.2]OH)-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])--(<:[:150,1.4]HO)-)}}{\hspace{4.5zw}化合物\gt{S}}}}}}

\br{1}

{\nousece\setatomsep{10pt}\chemname{\chemfig{*6(--(*6(---(*6(-(*5(-----))-----))---))----)}}{ステロイド骨格}}\hspace{2zw}\chemfig{C(<[1,1.4]X)(-[3,1.4]W)(-[5,1.4]Z)(<:[7,1.4]Y)}\hspace{2zw}\parbox{25zw}{\ce{W}，\ce{C}，\ce{Z}が紙面上にある時，\ce{X}は紙面の手前に，\\\ce{Y}は紙面の向こう側にある。}

\br{1}

図３−１

\br{1}

{\nousece\setatomsep{10pt}\setbondoffset{0pt}\chemname[-1zw]{\chemfig{*6((=[:210,1.2]O)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30](<[2,1]-[2,0.5,,,draw=none]OH)-[:-30](<[6,1]-[6,0.5,,,draw=none]OH)-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])---)}}{\hspace{4.5zw}\gt{１}}}\hspace{2zw}{\nousece\setatomsep{10pt}\setbondoffset{2pt}\chemname[-1zw]{\chemfig{*6((<[:210,1.4]HO)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30]-[:-30]-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])---)}}{\hspace{4.5zw}\gt{２}}}

\br{1}

{\nousece\setatomsep{10pt}\setbondoffset{2pt}\chemname[-1zw]{\chemfig{*6((<:[:210,1.4]HO)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30](<[2,1.4]OH)-[:-30](<[6,1.4]OH)-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])---)}}{\hspace{4.5zw}\gt{３}}}\hspace{2zw}{\nousece\setatomsep{10pt}\setbondoffset{2pt}\chemname[-1zw]{\chemfig{*6((<[:210,1.4]HO)--(*6(---(*6(-(*5(---(-[2](<:[:150])-[:30](<[2,1.4]OH)-[:-30]-[:30](<[2])-[:-30](-[6])-[:30])--))-(<[2])----))---))-(<[2])---)}}{\hspace{4.5zw}\gt{４}}}

\br{1}

図３−２

\br{1}

\begin{tikzpicture}
\draw (0,2) -- (0,0) -- ++(3,0) -- ++(0,2);
\draw (0,1.7) -- +(3,0);
\filldraw [fill=black!30!white,draw=black] (0.75,15pt) -- ++(0,-15pt) -- ++(1.5,0) -- ++(0,15pt) -- cycle;
\node at (1.5,0) [anchor=south] {\ce{CuS}};
\draw [->,>=stealth'] (1.25,15pt) -- +(-5pt,0.5) node [anchor=south east,inner sep=0pt] {\ce{Cu^2+}};
\draw [->,>=stealth'] (1.75,15pt) -- +(5pt,0.5) node [anchor=south west,inner sep=0pt] {\ce{S^2-}};
\draw (2.5,0.75) -- +(1.5,-0.5) node [anchor=west] {$\pH=2.0$（固定）};
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\draw [->,>=stealth'] (0,-0.5) -- +(0,3.5) node [anchor=east] {$\bun{1}{v}$};
\draw [->,>=stealth'] (-1.5,0) -- +(4.5,0) node [anchor=west] {$\bun{1}{[\ce{S}]}$};
\node at (0,0) [anchor=north east] {O};
\fill [fill=black] (5pt,1) circle [radius=2pt];
\fill [fill=black] (20pt,1.1) circle [radius=2pt];
\fill [fill=black] (36pt,1.3) circle [radius=2pt];
\fill [fill=black] (42pt,1.4) circle [radius=2pt];
\fill [fill=black] (55pt,2.2) circle [radius=2pt];
\draw [very thick] (-1.5,-0.3) -- node [right=1.2] {傾き：$\bun{\rmK_{\rmm}}{V_{\rm{max}}}$} (3,2.5);
\draw [->,>=stealth'] (1,0.5) node [anchor=west] {$\bun{1}{V_{\rm{max}}}$} -- (2.5pt,0.5);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path
coordinate (B) at (0,0)
coordinate (C) at ($(B)+(4,0)$)
coordinate (D) at ($(C)+(0.7,1.7)$)
coordinate (E) at ($(B)+(0.7,1.7)$)
coordinate (A) at ($(B)!.5!(D)+(0,2)$)
coordinate (F) at ($(B)!.5!(D)+(0,-2)$);
\draw [dashed] (B) -- (C) -- (D) -- (E) -- cycle;
\draw [dashed] (A) -- (B) -- (F) -- (C) -- cycle;
\draw [dashed] (A) -- (D) -- (F) -- (E) -- cycle;
\node at ($(A)!.5!(F)$) {\ce{Co^3+}};
\draw [->,>=stealth'] (A) node [fill=white,xshift=7pt] {\ce{NH3}} -- ($(A)!.5!(F)+(0,10pt)$);
\draw [->,>=stealth'] (B) node [fill=white,xshift=-5pt] {\ce{H3N}} -- ($(B)!.4!(D)$);
\draw [->,>=stealth'] (C) node [fill=white,xshift=6pt] {\ce{NH3}} -- ($(C)!.4!(E)$);
\draw [->,>=stealth'] (D) node [fill=white,xshift=6pt] {\ce{NH3}} -- ($(D)!.4!(B)$);
\draw [->,>=stealth'] (E) node [fill=white,xshift=-5pt] {\ce{H3N}} -- ($(E)!.4!(C)$);
\draw [->,>=stealth'] (F) node [fill=white,xshift=7pt] {\ce{NH3}} -- ($(F)!.5!(A)+(0,-10pt)$);
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path
coordinate (a1) at (0,0)
coordinate (a2) at ($(a1)+(0,-4.5)$)
coordinate (b1) at ($(a1)+(3.75,0)$)
coordinate (b2) at ($(b1)+(0,-4.5)$)
coordinate (c1) at ($(b1)+(3.75,0)$)
coordinate (c2) at ($(c1)+(0,-4.5)$)
coordinate (d1) at ($(c1)+(3.75,0)$)
coordinate (d2) at ($(d1)+(0,-4.5)$);
\foreach \point in {a1,b1,c1,d1}
\draw ($(\point)+(0,3.5)$) -- node [left=1pt] {\rotatebox{90}{$\log_{10}(K/K_0)$}} (\point) -- node [below=1pt] {$1/T$} ($(\point)+(2.5,0)$);
\foreach \point in {a2,b2,c2,d2}
\draw ($(\point)+(0,3.5)$) -- node [left=1pt] {\rotatebox{90}{$\log_{10}(k_3/k_0)$}} (\point) -- node [below=1pt] {$1/T$} ($(\point)+(2.5,0)$);
\foreach \point in {a1,a2,b1,b2,c1,c2,d1,d2}
{\foreach \x in {0.9,1.8}
\draw ($(\point)+(\x,0)$) -- +(0,5pt);
\foreach \y in {0.9,1.8,2.7}
\draw ($(\point)+(0,\y)$) -- +(5pt,0);}
\draw [very thick] ($(a1)+(0.45,0.7)$) -- +(1.7,2.2);
\draw [very thick] ($(a2)+(0.45,1.8)$) -- +(1.7,-0.4);
\draw [very thick] ($(b1)+(0.45,1.8)$) -- +(1.7,0.5);
\draw [very thick] ($(b2)+(0.45,2.7)$) -- +(1.7,-2);
\draw [very thick] ($(c1)+(0.45,2.7)$) -- +(1.7,-2);
\draw [very thick] ($(c2)+(0.45,1.8)$) -- +(1.7,-0.45);
\draw [very thick] ($(d1)+(0.45,2.3)$) -- +(1.7,-0.45);
\draw [very thick] ($(d2)+(0.45,2.7)$) -- +(1.7,-1.8);
\node at ($(a1)+(1.25,4)$) {\ajMarualph{a}};
\node at ($(b1)+(1.25,4)$) {\ajMarualph{b}};
\node at ($(c1)+(1.25,4)$) {\ajMarualph{c}};
\node at ($(d1)+(1.25,4)$) {\ajMarualph{d}};
\foreach \point in {a2,b2,c2,d2}
\draw ($(\point)+(-0.8,-0.8)$) -- ++(3.5,0) -- ++(0,9.8) -- ++(-3.5,0) -- cycle;
\end{tikzpicture}

\br{1}

\begin{tikzpicture}
\path
coordinate (ビーカー下中心) at (0,0)
coordinate (雫上端) at ($(ビーカー下中心)+(0.5,4.5)$)
coordinate (カラム左上) at ($(雫上端)+(-11.25pt,6.5)+(-4pt,0)$)
coordinate (左角) at ($(カラム左上)+(0,-4.5)$);
\draw (ビーカー下中心) circle [x radius=1.5,y radius=0.5];
\draw ($(ビーカー下中心)+(0,1.7)$) circle [x radius=1.5,y radius=0.5];
\draw ($(ビーカー下中心)+(-1.5,0)$) -- ++(0,2.8) .. controls +(0pt,5pt) .. +(-2pt,10pt);
\draw ($(ビーカー下中心)+(1.5,0)$) -- ++(0,2.8) .. controls +(0pt,5pt) .. +(2pt,10pt);
\draw ($(ビーカー下中心)+(-0.45,2.45)$) .. controls +(-1pt,3pt) and +(3pt,-1pt) .. +(-10pt,10pt) arc [start angle=240,end angle=-95,x radius=1.6,y radius=0.5] .. controls +(-3pt,-0.5pt) and +(3pt,0) .. ++(-10pt,-9pt) .. controls +(-3pt,0) and +(2pt,-1pt) .. ++(-7pt,9pt);
\draw (雫上端) .. controls +(0,-1.5pt) and +(0.3pt,1pt) .. ++(-1.5pt,-7pt) ..controls +(-0.3pt,-1pt) and +(-3pt,0) .. ($(雫上端)+(0,-13pt)$) .. controls +(3pt,0) and +(0.3pt,-1pt) .. ($(雫上端)+(1.5pt,-7pt)$) .. controls +(-0.3pt,1pt) and +(0,-1.5pt) .. cycle;
\fill [fill=black!30!white] ($(カラム左上)+(0,-1.5)$) -- (左角) arc [start angle=180,end angle=270,radius=11.25pt] -- ++(8pt,0) arc [start angle=270,end angle=360,radius=11.25pt] -- ++(0,3) -- cycle;
\draw (カラム左上) -- ++(0,-4.5) arc [start angle=180,end angle=270,radius=11.25pt] -- ++(0,-1) arc [start angle=180,end angle=360,x radius=4pt,y radius=2pt] -- ++(0,1) arc [start angle=270,end angle=360,radius=11.25pt] -- +(0,4.5);
\foreach \x in {3,6,...,27}
\foreach \y in {0,5,...,90}
\fill [fill=black] ($(左角)+(0.5pt,-5pt)+(\x pt,\y pt)$) circle [radius=0.5pt];
\foreach \x in {3,6,...,30}
\foreach \y in {0,5,...,85}
\fill [fill=black] ($(左角)+(-1pt,-2.5pt)+(\x pt,\y pt)$) circle [radius=0.5pt];
\fill [fill=black!30!white] (左角) arc [start angle=180,end angle=270,radius=11.25pt] -- ++(8pt,0) arc [start angle=270,end angle=360,radius=11.25pt] arc [start angle=0,end angle=-180,x radius=15.25pt,y radius=3pt] -- cycle;
\draw ($(左角)+(11.25pt,-11.25pt)$) arc [start angle=270,end angle=180,radius=11.25pt] arc [start angle=180,end angle=360,x radius=15.25pt,y radius=3pt] arc [start angle=0,end angle=-90,radius=11.25pt];
\filldraw [fill=white] ($(雫上端)+(0,5)$) ellipse [x radius=15.25pt,y radius=3pt];
\filldraw [fill=white] ($(雫上端)+(0,6)$) ellipse [x radius=15.25pt,y radius=3pt];
\draw ($(ビーカー下中心)+(1,1)$) -- +(0.75,0) node [anchor=west] {\mbox{\tate 溶出液}};
\draw ($(雫上端)+(0,1.8)$) -- +(0.75,0) node [anchor=west] {\mbox{\tate フィルター}};
\draw ($(カラム左上)+(0.3,-3)$) -- +(-0.75,0) node [anchor=east] {\mbox{\tate 陽イオン交換樹脂}};
\draw ($(雫上端)+(0,5.5)$) -- +(0.75,0) node [anchor=west] {\mbox{\tate ろ液}};
\end{tikzpicture}











\end{center}

\end{document}